EPR study of paramagnetic rhenium(I) complexes (bpy.-)Re(CO)3X relevant to the mechanism of electrocatalytic CO2 reduction
T. Scheiring, A. Klein, und W. Kaim. Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry, (1997)
Zusammenfassung
In situ redn. of fac-(bpy)Re(CO)3Cl, bpy = 2,2'-bipyridine, at a platinum cathode under CO2 atmosphere in acetonitrile or acetone has produced a series of distinct EPR spectra which are attributed to (bpy.-) contg. species and which invariably reveal the interaction of the unpaired electron with the metal nuclei (185,187Re, I=5/2). The EPR investigation of various model complexes (bpy.-)Re(CO)3X, generated by electrochem. redn. under argon of diamagnetic precursors (bpy)Re(CO)3X, X = Cl-, CF3SO3-, CH3O-, H-, THF, CH3CN, CO, HCO2-, HCO3- and CH3C(O)- has been used to interpret the results from the reactions under CO2 atmosphere. on SciFinder(R)
%0 Journal Article
%1 Scheiring.1997
%A Scheiring, Thomas
%A Klein, Axel
%A Kaim, Wolfgang.
%D 1997
%J Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry
%K EPR bipyridyl carbon carbonyl complex dioxide electrocatalytic redn;paramagnetic rhenium
%N 12
%P 2569--2571
%T EPR study of paramagnetic rhenium(I) complexes (bpy.-)Re(CO)3X relevant to the mechanism of electrocatalytic CO2 reduction
%X In situ redn. of fac-(bpy)Re(CO)3Cl, bpy = 2,2'-bipyridine, at a platinum cathode under CO2 atmosphere in acetonitrile or acetone has produced a series of distinct EPR spectra which are attributed to (bpy.-) contg. species and which invariably reveal the interaction of the unpaired electron with the metal nuclei (185,187Re, I=5/2). The EPR investigation of various model complexes (bpy.-)Re(CO)3X, generated by electrochem. redn. under argon of diamagnetic precursors (bpy)Re(CO)3X, X = Cl-, CF3SO3-, CH3O-, H-, THF, CH3CN, CO, HCO2-, HCO3- and CH3C(O)- has been used to interpret the results from the reactions under CO2 atmosphere. on SciFinder(R)
@article{Scheiring.1997,
abstract = {In situ redn. of fac-(bpy)Re(CO)3Cl, bpy = 2,2'-bipyridine, at a platinum cathode under CO2 atmosphere in acetonitrile or acetone has produced a series of distinct EPR spectra which are attributed to (bpy.-) contg. species and which invariably reveal the interaction of the unpaired electron with the metal nuclei (185,187Re, I=5/2). The EPR investigation of various model complexes (bpy.-)Re(CO)3X, generated by electrochem. redn. under argon of diamagnetic precursors (bpy)Re(CO)3X, X = Cl-, CF3SO3-, CH3O-, H-, THF, CH3CN, CO, HCO2-, HCO3- and CH3C(O)- has been used to interpret the results from the reactions under CO2 atmosphere. [on SciFinder(R)]},
added-at = {2019-07-15T13:41:23.000+0200},
author = {Scheiring, Thomas and Klein, Axel and Kaim, Wolfgang.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/21e663b79f334ef8355cdcaa117b38da7/b_schwederski},
interhash = {f7f3e4a4c81a0076070ccae0cb8e0884},
intrahash = {1e663b79f334ef8355cdcaa117b38da7},
issn = {0300-9580},
journal = {Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry},
keywords = {EPR bipyridyl carbon carbonyl complex dioxide electrocatalytic redn;paramagnetic rhenium},
number = 12,
pages = {2569--2571},
timestamp = {2019-07-15T11:42:10.000+0200},
title = {EPR study of paramagnetic rhenium(I) complexes (bpy.-)Re(CO)3X relevant to the mechanism of electrocatalytic CO2 reduction},
year = 1997
}