%0 Journal Article %1 Scheiring.1997 %A Scheiring, Thomas %A Klein, Axel %A Kaim, Wolfgang. %D 1997 %J Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry %K EPR bipyridyl carbon carbonyl complex dioxide electrocatalytic redn;paramagnetic rhenium %N 12 %P 2569--2571 %T EPR study of paramagnetic rhenium(I) complexes (bpy.-)Re(CO)3X relevant to the mechanism of electrocatalytic CO2 reduction %X In situ redn. of fac-(bpy)Re(CO)3Cl, bpy = 2,2'-bipyridine, at a platinum cathode under CO2 atmosphere in acetonitrile or acetone has produced a series of distinct EPR spectra which are attributed to (bpy.-) contg. species and which invariably reveal the interaction of the unpaired electron with the metal nuclei (185,187Re, I=5/2). The EPR investigation of various model complexes (bpy.-)Re(CO)3X, generated by electrochem. redn. under argon of diamagnetic precursors (bpy)Re(CO)3X, X = Cl-, CF3SO3-, CH3O-, H-, THF, CH3CN, CO, HCO2-, HCO3- and CH3C(O)- has been used to interpret the results from the reactions under CO2 atmosphere. on SciFinder(R)

@article{Scheiring.1997, abstract = {In situ redn. of fac-(bpy)Re(CO)3Cl, bpy = 2,2'-bipyridine, at a platinum cathode under CO2 atmosphere in acetonitrile or acetone has produced a series of distinct EPR spectra which are attributed to (bpy.-) contg. species and which invariably reveal the interaction of the unpaired electron with the metal nuclei (185,187Re, I=5/2). The EPR investigation of various model complexes (bpy.-)Re(CO)3X, generated by electrochem. redn. under argon of diamagnetic precursors (bpy)Re(CO)3X, X = Cl-, CF3SO3-, CH3O-, H-, THF, CH3CN, CO, HCO2-, HCO3- and CH3C(O)- has been used to interpret the results from the reactions under CO2 atmosphere. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Scheiring, Thomas and Klein, Axel and Kaim, Wolfgang.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/21e663b79f334ef8355cdcaa117b38da7/huebleriac}, interhash = {f7f3e4a4c81a0076070ccae0cb8e0884}, intrahash = {1e663b79f334ef8355cdcaa117b38da7}, issn = {0300-9580}, journal = {Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry}, keywords = {EPR bipyridyl carbon carbonyl complex dioxide electrocatalytic redn;paramagnetic rhenium}, number = 12, pages = {2569--2571}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {EPR study of paramagnetic rhenium(I) complexes (bpy.-)Re(CO)3X relevant to the mechanism of electrocatalytic CO2 reduction}, year = 1997 }