Variable structure of the Cu2S2 core in doubly thiolate-bridged dicopper(I) complexes. An x-ray crystallographic, electrochemical and EPR study of (dmp)2(o-CH3C6H4S)2Cu2, dmp = 2,9-dimethyl-1,10-phenanthroline, and a comment on the nature of phenanthroline-containing \dqCu(0)\dq complexes. Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences, (50)1:115--122, 1995. [PUMA: dinuclear toluenethiolate;electrochem complex;thiolate toluene phenanthroline crystal complex copper dimethylphenanthroline deriv structure]
Variable coordination of redox-active TCNB in discrete and polymeric ferrocenylcopper(i) complexes: Structures and spectroelectrochemical behaviour. Dalton Transactions, (42)45:16142--16150, 2013. [PUMA: phosphinoferrocene tetracyanobenzene crystal copper mol macrocycle spectroelectrochem prepn structure]
Unusual stabilization of anion radicals by copper(I). Special Publication - Royal Society of Chemistry, (131)Chemistry of the Copper and Zinc Triads:248--251, 1993. [PUMA: anion review;crystal stabilized review;pyridylterazine stabilization radical copper review;review review;phenanthrolinesemidione phosphine azodicarboxylate structure]
Three-spin system with a twist: A bis(semiquinonato)copper complex with a nonplanar configuration at the copper(II) center. Angewandte Chemie, International Edition, (44)14:2103--2106, 2005. [PUMA: methylthioanilinosemiquinonate;EPR nonplanar crystal ligand;magnetic radical copper property methylthioanilinosemiquinonate configuration;electrochem redox prepn structure]
The first structural characterization of an azoaromatic radical anion stabilized by dicopper(I) coordination. Angewandte Chemie, International Edition, (37)17:2403--2404, 1998. [PUMA: dinuclear azochloropyrimidine triphenylphosphine dinuclear;redn copper phenylphosphine potential structure;crystal prepn structure]
The First Crystal Structure of a Metal-Stabilized Tetrazine Anion Radical: Formation of a Dicopper Complex through Self-Assembly in a Comproportionation Reaction. Inorganic Chemistry, (38)10:2242--2243, 1999. [PUMA: dinuclear pyridyltetrazine copper phosphine structure;crystal prepn structure]
The dinuclear CuA center in cytochrome c oxidase and N2O reductase. A metal-metal bond in biology?. Angewandte Chemie, International Edition in English, (34)7:771--773, 1995. [PUMA: dinuclear center protein copper review]
The copper(I)/copper(II) transition in complexes with 8-alkylthioquinoline based multidentate ligands. Dalton Transactions, 2:189--202, 2003. [PUMA: quinolylsulfanyldioxaoctane complex copper redn complex;electrochem sulfanylquinoline quinolinylsulfanylmethylbenzene structure;crystal quinolylsulfanyloxapentane prepn structure]
The chemistry and biochemistry of the copper-radical interaction. Dalton Transactions, 5:761--768, 2003. [PUMA: chem radical copper review interaction biochem enzyme]
Tetranuclear complexes (μ4-TCNX)Cu(Me3TACN)4(BF4)4 with TCNX = TCNE, TCNQ or TCNB (1,2,4,5-tetracyanobenzene) and Me3TACN = 1,4,7-trimethyl-1,4,7-triazacyclononane. Inorganica Chimica Acta, (314)1-2:22--26, 2001. [PUMA: IR;IR triazacyclononane tetranuclear;TCNB tetranuclear IR copper electrochem tetranitrile IR;TCNQ redn;TCNE prepn]
TeS2·- radical anions in CuBrCu1.2TeS2. Angewandte Chemie, International Edition, (37)13/14:1955--1957, 1998. [PUMA: bromide thiotellurate copper ESR;crystal dithiotellurate prepn structure]
Synthetic and spectroscopic approaches to the copper/quinone-coupled center in amine oxidases: Bioinorg. Chem. In Jochen Rall, Eberhard Waldhor, Brigitte Schwederski, Manuela Schwach, Stephan Kohlmann, and Wolfgang. Kaim (Eds.), Wiley-VCH Verlag GmbH, 1997. [PUMA: benzoquinone oxidase methylthiomethylbenzimidazole;copper copper amine tautomerism;review model valence quinone methylthiomethylbenzimidazole prepn]
Stabilizing the elusive ortho-quinone/copper(I) oxidation state combination through p/p interaction in an isolated complex. Journal of the American Chemical Society, (130)46:15230--15231, 2008. [PUMA: diphenylphosphinoferrocene ortho monovalent complex copper complex;mol phenanthrenequinone structure;crystal quinone prepn structure]
Stabilization of biochemically interesting intermediates by metal coordination. 5. Complexes of zinc, copper(I), rhenium(I), and ruthenium(II) with singly reduced 2,5-diacetylpyrazine. Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, (85)12:4075--4082, 1989. [PUMA: rhenium reaction ESR chelate radical metal coordination anion ruthenium complex;diacetylpyrazine metal;redox copper zinc]
Spectroelectrochemistry of aromatic ligands and their derivatives. III. Binuclear transition metal complexes of copper(I), molybdenum(0), and rhenium(I) with 2,2'-bipyrimidine. Erratum to document cited in CA116(2):12392f. Journal of Organometallic Chemistry, (424)1:C2, 1992. [PUMA: rhenium visible Erratum complex metal redn bipyrimidine carbonyl transition Erratum;Erratum spectrum potential;molybdenum copper electronic electroredn]
Spectroelectrochemistry of aromatic ligands and their derivatives. III. Binuclear transition metal complexes of copper(I), molybdenum(0), and rhenium(I) with 2,2'-bipyrimidine. Journal of Organometallic Chemistry, (411)1-2:207--213, 1991. [PUMA: rhenium visible complex metal redn bipyrimidine carbonyl spectrum binuclear electroredn;transition copper spectrum;molybdenum potential electronic]
Silver(I), copper(I) and copper(II) complex of the new N,Se-chelate ligand 2-phenylselenomethyl-1H-benzimidazole: Electrochemistry and structure. Zeitschrift fuer Anorganische und Allgemeine Chemie, (635)6-7:1001--1007, 2009. [PUMA: voltammetry complex;silver complex;cyclic crystal complex copper phenylselenomethylbenzimidazole silver prepn structure]
Sensitive valence tautomer equilibrium of paramagnetic complexes (L)Cun+(Qn-) (n = 1 or 2; Q = quinones) related to amine oxidase enzymes. Chemistry - A European Journal, (5)10:2802--2809, 1999. [PUMA: oxidase complex complex;semiquinone valence catecholate structure benzoquinone triazacyclononane copper amine model isomerism;catecholate isomerism structure;copper isomerism;crystal prepn]
Self-assembly of trigonal-prismatic metallocages encapsulating BF4- or CuI32- as anionic guests: Structures and mechanism of formation. Angewandte Chemie, International Edition, (41)18:3371--3375, 2002. [PUMA: metallocage prepn;silver trisbenzimidazolylmethylbenzene benzimidazolylmethylbenzene fluoroborate ligand anion tridentate copper encapsulating prepn;copper silver prepn]
Reactivity of copper(I) complexes with tripodal ligands towards O2: Structures of a precursor L3CuI(NCCH3)(BF4), L3 = tris(3-isopropyl-4,5-trimethylenepyrazolyl)methane and of its oxidation product L3CuII(m-OH)2CuIIL3(BF4)2 with strong antiferromagnetic spin-spin coupling. Zeitschrift fuer Anorganische und Allgemeine Chemie, (631)13-14:2568--2574, 2005. [PUMA: dinuclear;magnetic complex hydroxy structure coupling dinuclear copper trimethylenepyrazolyl property acetonitrile complex;copper structure;crystal mononuclear methane antiferromagnetic prepn]