A review with 10 refs. discusses the stabilization of Cu(PPh3)2+ by 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine radical anion (L) and 4,7-phenanthroline-5,6-semidione (Q) as Cu(PPh3)22L+ (I) and Cu(PPh3)22Q+, resp., and of CuPh2P(CH2)6PPh2+ by Me3COC(O)NNC(O)OCMe3.bul. (Z) as CuPh2P(CH2)6PPh22Z (II). The crystal structures of I and II as BF4- salts are discussed. on SciFinder(R)
%0 Journal Article
%1 Kaim.1993
%A Kaim, W.
%A Moscherosch, M.
%A Kohlmann, S.
%A Field, J. S.
%A Fenske, D.
%D 1993
%J Special Publication - Royal Society of Chemistry
%K anion azodicarboxylate copper phosphine radical review;crystal review;phenanthrolinesemidione review;pyridylterazine review;review stabilization stabilized structure
%N Chemistry of the Copper and Zinc Triads
%P 248--251
%T Unusual stabilization of anion radicals by copper(I)
%V 131
%X A review with 10 refs. discusses the stabilization of Cu(PPh3)2+ by 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine radical anion (L) and 4,7-phenanthroline-5,6-semidione (Q) as Cu(PPh3)22L+ (I) and Cu(PPh3)22Q+, resp., and of CuPh2P(CH2)6PPh2+ by Me3COC(O)NNC(O)OCMe3.bul. (Z) as CuPh2P(CH2)6PPh22Z (II). The crystal structures of I and II as BF4- salts are discussed. on SciFinder(R)
@article{Kaim.1993,
abstract = {A review with 10 refs. discusses the stabilization of Cu(PPh3)2+ by 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine radical anion (L) and 4,7-phenanthroline-5,6-semidione (Q) as {[Cu(PPh3)2]2L}+ (I) and {[Cu(PPh3)2]2Q}+, resp., and of Cu[Ph2P(CH2)6PPh2]+ by Me3COC(O)NNC(O)OCMe3.bul. (Z) as {{Cu[Ph2P(CH2)6PPh2]}2Z} (II). The crystal structures of I and II as BF4- salts are discussed. [on SciFinder(R)]},
added-at = {2019-07-15T13:41:23.000+0200},
author = {Kaim, W. and Moscherosch, M. and Kohlmann, S. and Field, J. S. and Fenske, D.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2540240c0ea3adeb060f3d6c04440165a/b_schwederski},
interhash = {50ec6d0551633a83328f0b80ed0d9ee9},
intrahash = {540240c0ea3adeb060f3d6c04440165a},
issn = {0260-6291},
journal = {Special Publication - Royal Society of Chemistry},
keywords = {anion azodicarboxylate copper phosphine radical review;crystal review;phenanthrolinesemidione review;pyridylterazine review;review stabilization stabilized structure},
number = {Chemistry of the Copper and Zinc Triads},
pages = {248--251},
timestamp = {2019-07-15T11:42:10.000+0200},
title = {Unusual stabilization of anion radicals by copper(I)},
volume = 131,
year = 1993
}