%0 Journal Article %1 Kaim.1993 %A Kaim, W. %A Moscherosch, M. %A Kohlmann, S. %A Field, J. S. %A Fenske, D. %D 1993 %J Special Publication - Royal Society of Chemistry %K anion azodicarboxylate copper phosphine radical review;crystal review;phenanthrolinesemidione review;pyridylterazine review;review stabilization stabilized structure %N Chemistry of the Copper and Zinc Triads %P 248--251 %T Unusual stabilization of anion radicals by copper(I) %V 131 %X A review with 10 refs. discusses the stabilization of Cu(PPh3)2+ by 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine radical anion (L) and 4,7-phenanthroline-5,6-semidione (Q) as [Cu(PPh3)2]2L+ (I) and [Cu(PPh3)2]2Q+, resp., and of Cu[Ph2P(CH2)6PPh2]+ by Me3COC(O)NNC(O)OCMe3.bul. (Z) as Cu[Ph2P(CH2)6PPh2]2Z (II). The crystal structures of I and II as BF4- salts are discussed. [on SciFinder(R)]

@article{Kaim.1993, abstract = {A review with 10 refs. discusses the stabilization of Cu(PPh3)2+ by 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine radical anion (L) and 4,7-phenanthroline-5,6-semidione (Q) as {[Cu(PPh3)2]2L}+ (I) and {[Cu(PPh3)2]2Q}+, resp., and of Cu[Ph2P(CH2)6PPh2]+ by Me3COC(O)NNC(O)OCMe3.bul. (Z) as {{Cu[Ph2P(CH2)6PPh2]}2Z} (II). The crystal structures of I and II as BF4- salts are discussed. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Kaim, W. and Moscherosch, M. and Kohlmann, S. and Field, J. S. and Fenske, D.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2540240c0ea3adeb060f3d6c04440165a/huebleriac}, interhash = {50ec6d0551633a83328f0b80ed0d9ee9}, intrahash = {540240c0ea3adeb060f3d6c04440165a}, issn = {0260-6291}, journal = {Special Publication - Royal Society of Chemistry}, keywords = {anion azodicarboxylate copper phosphine radical review;crystal review;phenanthrolinesemidione review;pyridylterazine review;review stabilization stabilized structure}, number = {Chemistry of the Copper and Zinc Triads}, pages = {248--251}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Unusual stabilization of anion radicals by copper(I)}, volume = 131, year = 1993 }