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Boron Atoms as Spin Carriers in Two- and Three-Dimensional Systems

W. Kaim, N. Hosmane, S. Zalis, J. Maguire, and W. Lipscomb. Angewandte Chemie, International Edition, 48 (28): 5082--5091 (2009)
DOI: 10.1002/anie.200803493

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Chemistry of C-Trimethylsilyl-Substituted Heterocarboranes. 30. Synthetic and Structural Studies on Oxide Ion Encapsulating Tetralanthanide Tetrahedra Surrounded by \dqCarbons Apart\dq C2B4-Carborane Ligands (Ln(III) = La, Nd, Gd, Tb, Ho, Lu)J. Wang, S. Li, C. Zheng, A. Li, N. Hosmane, J. Maguire, H. Roesky, C. Cummins, and W. Kaim. Organometallics, 23 (20): 4621--4629 (2004)Chemistry of C-Trimethylsilyl-Substituted Heterocarboranes. 21. Syntheses, Structures, EPR Spectra, and Reactivities of Bent-Sandwich and Half-Sandwich Titanacarboranes. Full Analysis of Spin-Spin Coupling in Two Structurally Characterized Titanium(III)-Carborane DimersN. Hosmane, Y. Wang, H. Zhang, K. Lu, J. Maguire, T. Gray, K. Brooks, E. Waldhoer, W. Kaim, and R. Kremer. Organometallics, 16 (7): 1365--1377 (1997)Synthesis and crystal structure of a novel, TMEDA-stabilized closo-cobalt(II) carborane: An intermediate for anionic, commo-cobalt(III) carborane complexesN. Hosmane, Y. Wang, H. Zhang, J. Maguire, E. Waldhoer, and W. Kaim. Organometallics, 12 (10): 3785--3787 (1993)Electron-Acceptor Behavior of 2,4,7,9-Tetracarba-nido-dodecaborane(12) with Group 1 and Group 2 Metals: Syntheses and Crystal Structures of (THF)4Li(SiMe3)4C4B8H9 and (THF)2Mg(SiMe3)4C4B8H8N. Hosmane, W. Kaim, Y. Wang, K. Lu, C. Thomas, M. Ezhova, S. Helfert, J. Collins, J. Maguire, and T. Gray. Organometallics, 15 (10): 2425--2427 (1996)Synthesis and Crystal Structure of the First Polymeric Cesium Compound of a Carborane Ligand SystemN. Hosmane, T. Demissie, H. Zhang, J. Maguire, W. Lipscomb, F. Baumann, and W. Kaim. Organometallics, 17 (3): 293--295 (1998)Chemistry of C-Trimethylsilyl-Substituted Heterocarboranes. 29. Synthetic and Structural Studies on Lanthanacarboranes with Two and Three \dqCarbons Apart\dq Carborane Cages Bonding to Ln(III) Metal (Ln(III) = Nd, Gd, Dy, Ho, Er, Tb, Lu)J. Wang, S. Li, C. Zheng, J. Maguire, B. Sarkar, W. Kaim, and N. Hosmane. Organometallics, 22 (21): 4334--4342 (2003)Chemistry of C-Trimethylsilyl-Substituted Heterocarboranes. 31. New Insights into Reaction Pathways of Carborane Ligand Systems: Synthetic, Structural, Spectroscopic, and Electrochemical Studies on Sandwich and Half-Sandwich Metallacarboranes of Iron, Cobalt, and NickelS. Tomlinson, C. Zheng, N. Hosmane, J. Yang, Y. Wang, H. Zhang, T. Gray, T. Demissie, J. Maguire, F. Baumann and 4 other author(s). Organometallics, 24 (9): 2177--2187 (2005)Stereospecific Intramolecular S$\rightarrow$Pt Transmethylation from 8-(Methylthio)quinoline to Coordinated PtMe2: Formation of syn-fac-PtIVMe3(m-8-quinolinethiolato)2 with Stacked Quinoline RingsS. Ye, W. Kaim, M. Niemeyer, and N. Hosmane. Organometallics, 24 (5): 794--796 (2005)An oxide ion encapsulating tetraholmium tetrahedron stabilized by complexation with the \dqcarbons apart\dq C2B4-carborane ligands. Erratum to document cited in CA139:381606J. Wang, S. Li, C. Zheng, N. Hosmane, J. Maguire, H. Roesky, C. Cummins, and W. Kaim. Organometallics, 23 (10): 2514 (2004)Boron Atoms as Spin Carriers in Two- and Three-Dimensional SystemsW. Kaim, N. Hosmane, S. Zalis, J. Maguire, and W. Lipscomb. Angewandte Chemie, International Edition, 48 (28): 5082--5091 (2009)