%0 Journal Article %1 Hosmane.1995 %A Hosmane, Narayan S. %A Wang, Ying %A Zhang, Hongming %A Oki, Aderemi R. %A Maguire, John A. %A Waldhoer, Eberhard %A Kaim, Wolfgang %A Binder, Herbert %A Kremer, Reinhard K. %D 1995 %J Organometallics %K bent carborane crystal erbium mol prepn sandwich sandwich;erbium structure %N 3 %P 1101--1103 %R 10.1021/om00003a009 %T A Systematic Synthetic Approach to a Novel, Mixed 2,3-C2B4- and 2,4-C2B4-Erbium(III) Carborane Bent-Sandwich Complex %V 14 %X The reaction between closo-exo-Li(TMEDA)-1-Li(TMEDA)-2,3-(SiMe3)2-2,3-C2B4H4 (1a) and anhyd. ErCl3, in a molar ratio of 2:1, in dry benzene at 0° produced, in 93\% yield, a novel Er(III) bent-sandwich complex, [Li(TMEDA)2][1-Cl-1-(m-Cl)-2,2',3,3'-(SiMe3)4-5,6-[(m-H)2Li(TMEDA)]-4,4',5'-[(m-H)3Li(TMEDA)]-1,1'-common-Er(2,3-C2B4H4)2] (2), as an orange cryst. solid. The reaction of 2 with 1 equiv of closo-exo-Li(TMEDA)-1-Li(TMEDA)-2,4-(SiMe3)2-2,4-C2B4H4 (1b) in dry benzene at 0° produces the pink, dimeric Er(III) mixed-carborane bent-sandwich complex Li(TMEDA)22common-1-[2,3-(SiMe3)2-2,3-C2B4H4]-1-Er-[2,4-(SiMe3)2-2,4-C2B4H4]2 (3) in 95\% yield, thus demonstrating a possible general synthetic route to mixed-carborane metal complexes. The crystal structures of 2 and 3 were detd. [on SciFinder(R)]

@article{Hosmane.1995, abstract = {The reaction between closo-exo-Li(TMEDA)-1-Li(TMEDA)-2,3-(SiMe3)2-2,3-C2B4H4 (1a) and anhyd. ErCl3, in a molar ratio of 2:1, in dry benzene at 0° produced, in 93{\%} yield, a novel Er(III) bent-sandwich complex, [Li(TMEDA)2][1-Cl-1-(\textgreek{m}-Cl)-2,2',3,3'-(SiMe3)4-5,6-[(\textgreek{m}-H)2Li(TMEDA)]-4,4',5'-[(\textgreek{m}-H)3Li(TMEDA)]-1,1'-common-Er(2,3-C2B4H4)2] (2), as an orange cryst. solid. The reaction of 2 with 1 equiv of closo-exo-Li(TMEDA)-1-Li(TMEDA)-2,4-(SiMe3)2-2,4-C2B4H4 (1b) in dry benzene at 0° produces the pink, dimeric Er(III) mixed-carborane bent-sandwich complex {Li(TMEDA)2}2{common-1-[2,3-(SiMe3)2-2,3-C2B4H4]-1-Er-[2,4-(SiMe3)2-2,4-C2B4H4]}2 (3) in 95{\%} yield, thus demonstrating a possible general synthetic route to mixed-carborane metal complexes. The crystal structures of 2 and 3 were detd. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Hosmane, Narayan S. and Wang, Ying and Zhang, Hongming and Oki, Aderemi R. and Maguire, John A. and Waldhoer, Eberhard and Kaim, Wolfgang and Binder, Herbert and Kremer, Reinhard K.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2b87ee15816c11a072a869bd396c6bb1e/huebleriac}, doi = {10.1021/om00003a009}, interhash = {12149d1711316b4d55b2558df2b4d8fd}, intrahash = {b87ee15816c11a072a869bd396c6bb1e}, issn = {0276-7333}, journal = {Organometallics}, keywords = {bent carborane crystal erbium mol prepn sandwich sandwich;erbium structure}, number = 3, pages = {1101--1103}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {A Systematic Synthetic Approach to a Novel, Mixed 2,3-C2B4- and 2,4-C2B4-Erbium(III) Carborane Bent-Sandwich Complex}, volume = 14, year = 1995 }