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Multistep redox sequences of azopyridyl (L) bridged reaction centers in stable radical complex ions (μ-L)[MCl(η5-C5Me5)]2$\surd$+, M = Rh or Ir: Spectroelectrochemistry and high-frequency EPR spectroscopy

S. Frantz, R. Reinhardt, S. Greulich, M. Wanner, J. Fiedler, C. Duboc-Toia, and W. Kaim. Dalton Transactions, (2003)
DOI: 10.1039/B305311C

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Stephanie Eigner University of Stuttgart

Stephanie Maier University of Stuttgart

Dr. -Ing. Stephanie Moritz University of Stuttgart

Stephanie Mrzyglod University of Stuttgart

Dr. rer. nat. Stephanie Essig University of Stuttgart

Other publications of authors with the same name

Multistep redox sequences of azopyridyl (L) bridged reaction centers in stable radical complex ions (μ-L)[MCl(η5-C5Me5)]2$\surd$+, M = Rh or Ir: Spectroelectrochemistry and high-frequency EPR spectroscopyS. Frantz, R. Reinhardt, S. Greulich, M. Wanner, J. Fiedler, C. Duboc-Toia, and W. Kaim. Dalton Transactions, (2003)Structure, electrochemistry, spectroscopy, and magnetic resonance, including high-field EPR, of (μ-abpy)[Re(CO)3X]2o/·-, where abpy = 2,2'-azobispyridine and X = F, Cl, Br, IS. Frantz, M. Sieger, I. Hartenbach, F. Lissner, T. Schleid, J. Fiedler, C. Duboc, and W. Kaim. Journal of Organometallic Chemistry, 694 (7-8): 1122--1133 (2009)Mechanism and product characterization from the electroreduction of heterodinuclear complexes [(C5Me5)ClM(m-L)Re(CO)3X](PF6), M = Rh or Ir, L = 2,2'-azobispyridine or 2,2'-azobis(5-chloropyrimidine), X = halideS. Frantz, M. Weber, T. Scheiring, J. Fiedler, C. Duboc, and W. Kaim. Inorganica Chimica Acta, 357 (10): 2905--2914 (2004)Multifrequency EPR Study and Density Functional g-Tensor Calculations of Persistent Organorhenium Radical ComplexesS. Frantz, H. Hartmann, N. Doslik, M. Wanner, W. Kaim, H. Kuemmerer, G. Denninger, A. Barra, C. Duboc-Toia, J. Fiedler and 3 other author(s). Journal of the American Chemical Society, 124 (35): 10563--10571 (2002)EPR insensitivity of the metal-nitrosyl spin-bearing moiety in complexes [LnRuII-NO.bul.]kS. Frantz, B. Sarkar, M. Sieger, W. Kaim, F. Roncaroli, J. Olabe, and S. Zalis. European Journal of Inorganic Chemistry, (2004)Proof of Innocence for the Quintessential Noninnocent Ligand TCNQ in Its Tetranuclear Complex with Four [fac-Re(CO)3(bpy)]+ Groups: Unusually Different Reactivity of the TCNX Ligands (TCNX = TCNE, TCNQ, TCNB)H. Hartmann, W. Kaim, M. Wanner, A. Klein, S. Frantz, C. Duboc-Toia, J. Fiedler, and S. Zalis. Inorganic Chemistry, 42 (22): 7018--7025 (2003)Metal-induced tautomerization of p- to o-quinone compounds: Experimental evidence from CuI and ReI complexes of azophenine and DFT studiesS. Frantz, J. Rall, I. Hartenbach, T. Schleid, S. Zalis, and W. Kaim. Chemistry - A European Journal, 10 (1): 149--154 (2004)Azo compounds as electron acceptor or radical ligands in transition metal species: Spectroelectrochemistry and high-field EPR studies of ruthenium, rhodium and copper complexes of 2,2'-azobis(5-chloropyrimidine)W. Kaim, N. Doslik, S. Frantz, T. Sixt, M. Wanner, F. Baumann, G. Denninger, H. Kummerer, C. Duboc-Toia, J. Fiedler and 1 other author(s). Journal of Molecular Structure, 656 (1-3): 183--194 (2003)Mixed-valent and radical states of complexes [(bpy)2M(m-abpy)M'(bpy)2]n+, M,M' = Ru or Os, abpy = 2,2'-azobispyridine: Electron transfer vs. hole transfer mechanism in azo ligand-bridged complexesM. Heilmann, S. Frantz, W. Kaim, J. Fiedler, and C. Duboc. Inorganica Chimica Acta, 359 (3): 821--829 (2006)A complete series of tricarbonylhalidorhenium(I) complexes (abpy)Re(CO)3(Hal), Hal = F, Cl, Br, I; abpy = 2,2'-azobispyridine: Structures, spectroelectrochemistry and EPR of reduced formsS. Frantz, J. Fiedler, I. Hartenbach, T. Schleid, and W. Kaim. Journal of Organometallic Chemistry, 689 (19): 3031--3039 (2004)

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