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Proof of Innocence for the Quintessential Noninnocent Ligand TCNQ in Its Tetranuclear Complex with Four fac-Re(CO)3(bpy)+ Groups: Unusually Different Reactivity of the TCNX Ligands (TCNX = TCNE, TCNQ, TCNB)

H. Hartmann, W. Kaim, M. Wanner, A. Klein, S. Frantz, C. Duboc-Toia, J. Fiedler, and S. Zalis. Inorganic Chemistry, 42 (22): 7018--7025 (2003)
DOI: 10.1021/ic034232l

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Silke Hartmann University of Stuttgart

Dr. Heiko Schulz University of Stuttgart

Dr. -Ing. Heiko Neher University of Stuttgart

Jan Hartmann University of Stuttgart

Dr. -Ing. Gabriele Hartmann University of Stuttgart

Other publications of authors with the same name

Reversible and Site-Specific Reduction of the Ligand Sides in a Molecular Rectangle with up to Eight ElectronsH. Hartmann, S. Berger, R. Winter, J. Fiedler, and W. Kaim. Inorganic Chemistry, 39 (21): 4977--4980 (2000)Electron transfer reactions of (C5R5)2(CO)2Ti (R = H or Me) with TCNE or TCNQ spectroelectrochemical assignment of metal and ligand oxidation states in (C5Me5)2(CO)Ti(TCNX)2-/-/o/+H. Hartmann, B. Sarkar, W. Kaim, and J. Fiedler. Journal of Organometallic Chemistry, 687 (1): 100--107 (2003)Multifrequency EPR Study and Density Functional g-Tensor Calculations of Persistent Organorhenium Radical ComplexesS. Frantz, H. Hartmann, N. Doslik, M. Wanner, W. Kaim, H. Kuemmerer, G. Denninger, A. Barra, C. Duboc-Toia, J. Fiedler and 3 other author(s). Journal of the American Chemical Society, 124 (35): 10563--10571 (2002)Long-range electronic coupling in various oxidation states of a C4-linked tris(b-diketonato)ruthenium dimerY. Hoshino, S. Higuchi, J. Fiedler, C. Su, A. Knodler, B. Schwederski, B. Sarkar, H. Hartmann, and W. Kaim. Angewandte Chemie, International Edition, 42 (6): 674--677 (2003)Proof of Innocence for the Quintessential Noninnocent Ligand TCNQ in Its Tetranuclear Complex with Four fac-Re(CO)3(bpy)+ Groups: Unusually Different Reactivity of the TCNX Ligands (TCNX = TCNE, TCNQ, TCNB)H. Hartmann, W. Kaim, M. Wanner, A. Klein, S. Frantz, C. Duboc-Toia, J. Fiedler, and S. Zalis. Inorganic Chemistry, 42 (22): 7018--7025 (2003)A fully characterized complex ion with unreduced TCNQ as fourfold bridging ligand. (m4-TCNQ)fac-Re(CO)3(bpy)44+H. Hartmann, W. Kaim, I. Hartenbach, T. Schleid, M. Wanner, and J. Fiedler. Angewandte Chemie, International Edition, 40 (15): 2842--2844 (2001)

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