%0 Journal Article %1 Frantz.2004e %A Frantz, Stephanie %A Fiedler, Jan %A Hartenbach, Ingo %A Schleid, Thomas %A Kaim, Wolfgang. %D 2004 %J Journal of Organometallic Chemistry %K 0 azobispyridine bromo carbonyl carbonyl;rhenium crystal fluoro halo iodo;ESR prepn reduced rhenium spectroelectrochem;spectroelectrochem structure %N 19 %P 3031--3039 %R 10.1016/j.jorganchem.2004.06.047 %T A complete series of tricarbonylhalidorhenium(I) complexes (abpy)Re(CO)3(Hal), Hal = F, Cl, Br, I; abpy = 2,2'-azobispyridine: Structures, spectroelectrochemistry and EPR of reduced forms %V 689 %X For the 1st time a complete set of tricarbonylhalidorhenium(I) complexes (Hal = F, Cl, Br, I) was studied in a systematical fashion by example of (abpy)Re(CO)3(Hal), abpy = 2,2'-azobispyridine. Crystal structures of chloride, bromide and iodide analogs are now available, showing increasing planarization of the abpy ligand in that order. Cyclic voltammetry, EPR, IR and UV/visible spectroelectrochem. of the reduced formed [(abpy)Re(CO)3(Hal)]·- illustrate that the four halide complexes differ only partially in their properties. The strongest deviations are obsd. for [(abpy)Re(CO)3F]·- which is distinguished by the widest electrochem. potential range but most pronounced chem. lability. In the EPR spectrum the fluoride exhibits the highest isotropic g value (2.0085) and the lowest Re coupling const., which is of the same magnitude (2 mT) as the detectable 19F hyperfine splitting. [on SciFinder(R)]

@article{Frantz.2004e, abstract = {For the 1st time a complete set of tricarbonylhalidorhenium(I) complexes (Hal = F, Cl, Br, I) was studied in a systematical fashion by example of (abpy)Re(CO)3(Hal), abpy = 2,2'-azobispyridine. Crystal structures of chloride, bromide and iodide analogs are now available, showing increasing planarization of the abpy ligand in that order. Cyclic voltammetry, EPR, IR and UV/visible spectroelectrochem. of the reduced formed [(abpy)Re(CO)3(Hal)]·- illustrate that the four halide complexes differ only partially in their properties. The strongest deviations are obsd. for [(abpy)Re(CO)3F]·- which is distinguished by the widest electrochem. potential range but most pronounced chem. lability. In the EPR spectrum the fluoride exhibits the highest isotropic g value (2.0085) and the lowest Re coupling const., which is of the same magnitude (2 mT) as the detectable 19F hyperfine splitting. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Frantz, Stephanie and Fiedler, Jan and Hartenbach, Ingo and Schleid, Thomas and Kaim, Wolfgang.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2a4bdf1a8409118ad521ab371a29c399f/huebleriac}, doi = {10.1016/j.jorganchem.2004.06.047}, interhash = {941ced56b91ff3c8df49c066234ada99}, intrahash = {a4bdf1a8409118ad521ab371a29c399f}, journal = {Journal of Organometallic Chemistry}, keywords = {0 azobispyridine bromo carbonyl carbonyl;rhenium crystal fluoro halo iodo;ESR prepn reduced rhenium spectroelectrochem;spectroelectrochem structure}, number = 19, pages = {3031--3039}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {A complete series of tricarbonylhalidorhenium(I) complexes (abpy)Re(CO)3(Hal), Hal = F, Cl, Br, I; abpy = 2,2'-azobispyridine: Structures, spectroelectrochemistry and EPR of reduced forms}, volume = 689, year = 2004 }