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2,2'-Dipyridylketone (dpk) as Ancillary Acceptor and Reporter Ligand in Complexes [(dpk)(Cl)Ru(m-tppz)Ru(Cl)(dpk)]n+ where tppz = 2,3,5,6-Tetrakis(2-pyridyl)pyrazine

S. Ghumaan, B. Sarkar, N. Chanda, M. Sieger, J. Fiedler, W. Kaim, and G. Lahiri. Inorganic Chemistry, 45 (19): 7955--7961 (2006)
DOI: 10.1021/ic060887l

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Verena Fiedler University of Stuttgart

Tim Janz University of Stuttgart

Benedikt Janny

PD Dr. phil. Frank Janle University of Stuttgart

Isabel Janowsky-Vidovic University of Stuttgart

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A Five-Center Redox System: Molecular Coupling of Two Noninnocent Imino-o-benzoquinonato-Ruthenium Functions through a p Acceptor BridgeA. Das, B. Sarkar, J. Fiedler, S. Zalis, I. Hartenbach, S. Strobel, G. Lahiri, and W. Kaim. Journal of the American Chemical Society, 131 (25): 8895--8902 (2009)Carboxylate Tolerance of the Redox-Active Platform [Ru(m-tppz)Ru]n, where tppz = 2,3,5,6-Tetrakis(2-pyridyl)pyrazine, in the Electron-Transfer Series [(L)ClRu(m-tppz)RuCl(L)]n, n = 2+, +, 0, -, and 2-, with 2-Picolinato, Quinaldato, and 8-Quinolinecarboxylato Ligands (L-)T. Kundu, B. Sarkar, T. Mondal, J. Fiedler, S. Mobin, W. Kaim, and G. Lahiri. Inorganic Chemistry, 49 (14): 6565--6574 (2010)Controlling metal-ligand-metal oxidation state combinations by ancillary ligand (L) variation in the redox systems [L2Ru(m-boptz)RuL2]n, boptz = 3,6-bis(2-hydroxyphenyl)-1,2,4,5-tetrazine(2-), and L = acetylacetonate, 2,2'-bipyridine, or 2-phenylazopyridineS. Patra, B. Sarkar, S. Maji, J. Fiedler, F. Urbanos, R. Jimenez-Aparicio, W. Kaim, and G. Lahiri. Chemistry - A European Journal, 12 (2): 489--498 (2006)The BIAN ligand 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene: An electron sponge or a \dqnormal\dq a-diimine ligand?I. Loew, M. Bubrin, A. Paretzki, J. Fiedler, S. Zalis, and W. Kaim. Inorganica Chimica Acta, 455 (Part\_2): 540--548 (2017)Organometallic iridium(III) and rhenium(I) complexes with lumazine, alloxazine and pterin derivativesO. Heilmann, F. Hornung, J. Fiedler, and W. Kaim. Journal of Organometallic Chemistry, 589 (1): 2--10 (1999)Di- and trinuclear complexes of WS42- with tricarbonylrhenium(I) and -manganese(I) fragments. Structure, spectroscopy, and electrochemistryW. Kaim, F. Hornung, R. Schaefer, B. Schwederski, and J. Fiedler. Zeitschrift fuer Anorganische und Allgemeine Chemie, 624 (7): 1211--1220 (1998)Structure and Spectroelectrochemical Response of Arene-Ruthenium and Arene-Osmium Complexes with Potentially Hemilabile Noninnocent LigandsM. Bubrin, D. Schweinfurth, F. Ehret, S. Zalis, H. Kvapilova, J. Fiedler, Q. Zeng, F. Hartl, and W. Kaim. Organometallics, 33 (18): 4973--4985 (2014)Electronic and molecular structure of 2,2'-bipyrimidine-bridged bis(organoplatinum) complexes in various oxidation states. Radical-bridged diplatinum species and the absence of a Pt(III)/Pt(II) mixed-valent intermediateA. Klein, W. Kaim, F. Hornung, J. Fiedler, and S. Zalis. Inorganica Chimica Acta, 264 (1-2): 269--278 (1997)2,5-Dioxido-1,4-benzoquinonediimine (H2L2-), a hydrogen-bonding noninnocent bridging ligand related to aminated topaquinone: Different oxidation state distributions in complexes [(bpy)2Ru2(m-H2L)]n (n = 0 , +, 2+, 3+, 4+) and [(acac)2Ru2(m-H2L)]m (m = 2-, -, 0, +, 2+)S. Kar, B. Sarkar, S. Ghumaan, D. Janardanan, J. van Slageren, J. Fiedler, V. Puranik, R. Sunoj, W. Kaim, and G. Lahiri. Chemistry - A European Journal, 11 (17): 4901--4911 (2005)Mechanism and product characterization from the electroreduction of heterodinuclear complexes [(C5Me5)ClM(m-L)Re(CO)3X](PF6), M = Rh or Ir, L = 2,2'-azobispyridine or 2,2'-azobis(5-chloropyrimidine), X = halideS. Frantz, M. Weber, T. Scheiring, J. Fiedler, C. Duboc, and W. Kaim. Inorganica Chimica Acta, 357 (10): 2905--2914 (2004)

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