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Metal-Induced Reductive Ring Opening of 1,2,4,5-Tetrazines: Three Resulting Coordination Alternatives, Including the New Non-Innocent 1,2-Diiminohydrazido(2-) Bridging Ligand System

S. Maji, B. Sarkar, S. Patra, J. Fiedler, S. Mobin, V. Puranik, W. Kaim, and G. Lahiri. Inorganic Chemistry, 45 (3): 1316--1325 (2006)
DOI: 10.1021/ic051532p

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Verena Fiedler University of Stuttgart

Tim Janz University of Stuttgart

Benedikt Janny

PD Dr. phil. Frank Janle University of Stuttgart

Isabel Janowsky-Vidovic University of Stuttgart

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Pseudo-base formation in the attempted synthesis of a conjugatively coupled bis(nitrosylruthenium) complex and spectroelectrochemistry of bipyrimidine-bridged dinuclear Ru(terpy)X precursor compounds (X = Cl, NO2)P. Singh, M. Sieger, J. Fiedler, C. Su, and W. Kaim. Dalton Transactions, (2008)A radical-bridged bis(ferrocenylcopper(I)) complex: Structural identity, multifrequency EPR, and spectroelectrochemistryS. Roy, M. Sieger, P. Singh, M. Niemeyer, J. Fiedler, C. Duboc, and W. Kaim. Inorganica Chimica Acta, 361 (6): 1699--1704 (2008)First characterization of a tetrathiomolybdate(V) derivative by EPR, UV-VIS and IR spectroelectrochemistryR. Schaefer, J. Fiedler, M. Moscherosch, and W. Kaim. Journal of the Chemical Society, Chemical Communications, (1993)2,5-Bis(1-phenyliminoethyl)pyrazine (bpip): A conjugated metal-metal bridging acceptor ligand and its homodinuclear complexes with low-valent metal centersA. Klein, V. Kasack, R. Reinhardt, T. Sixt, T. Scheiring, S. Zalis, J. Fiedler, and W. Kaim. Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry, (1999)Ligand-based Reduction in a Molecular Rectangle with Four Organoplatinum(IV) VerticesC. Kavakli, B. Schwederski, J. Fiedler, D. Gudat, and W. Kaim. Zeitschrift fuer Anorganische und Allgemeine Chemie, 636 (1): 114--120 (2010)The FeIII/FeII vs. Fe22.5 Formulation in Mixed-Valent Species [(NC)4Fe(BL)Fe(CN)4]3-, BL = 2,2'-Bipyrimidine and 3,6-Bis(2-pyridyl)-1,2,4,5-tetrazine. Distance and Size Do Not Always MatterM. Gloeckle, W. Kaim, N. Katz, M. Posse, E. Cutin, and J. Fiedler. Inorganic Chemistry, 38 (14): 3270--3274 (1999)What a Difference Ancillary Thienyl Makes: Unexpected Additional Stabilization of the Diruthenium(III,II) but Not the Diosmium(III,II) Mixed-Valent State in Tetrazine Ligand-Bridged ComplexesB. Sarkar, W. Kaim, A. Klein, B. Schwederski, J. Fiedler, C. Duboc-Toia, and G. Lahiri. Inorganic Chemistry, 42 (20): 6172--6174 (2003)Structure, electrochemistry, spectroscopy, and magnetic resonance, including high-field EPR, of (μ-abpy)[Re(CO)3X]2o/·-, where abpy = 2,2'-azobispyridine and X = F, Cl, Br, IS. Frantz, M. Sieger, I. Hartenbach, F. Lissner, T. Schleid, J. Fiedler, C. Duboc, and W. Kaim. Journal of Organometallic Chemistry, 694 (7-8): 1122--1133 (2009)A Five-Center Redox System: Molecular Coupling of Two Noninnocent Imino-o-benzoquinonato-Ruthenium Functions through a p Acceptor BridgeA. Das, B. Sarkar, J. Fiedler, S. Zalis, I. Hartenbach, S. Strobel, G. Lahiri, and W. Kaim. Journal of the American Chemical Society, 131 (25): 8895--8902 (2009)Carboxylate Tolerance of the Redox-Active Platform [Ru(m-tppz)Ru]n, where tppz = 2,3,5,6-Tetrakis(2-pyridyl)pyrazine, in the Electron-Transfer Series [(L)ClRu(m-tppz)RuCl(L)]n, n = 2+, +, 0, -, and 2-, with 2-Picolinato, Quinaldato, and 8-Quinolinecarboxylato Ligands (L-)T. Kundu, B. Sarkar, T. Mondal, J. Fiedler, S. Mobin, W. Kaim, and G. Lahiri. Inorganic Chemistry, 49 (14): 6565--6574 (2010)

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