Photoelectron spectra and molecular properties. 77. Radical ions, XXIII. R2P and R2N substituted benzenes: Charge distribution in their cations, anions, and trianions
W. Kaim, und H. Bock. Chemische Berichte, 111 (12):
3843--3856(1978)
Zusammenfassung
The photoelectron spectra of C6H4(PMe2)2-p (I) and its mono- and diamino analogs and the high-resoln. ESR spectra of their radical ions confirm the different acceptor or donor effects of the 2 substituents and yield information on charge distribution in the mol. states of the individual radical ions. I could be selectively reduced to the radical anion or trianion, but could not be oxidized to the radical cation. on SciFinder(R)
%0 Journal Article
%1 Kaim.1978c
%A Kaim, Wolfgang
%A Bock, Hans.
%D 1978
%J Chemische Berichte
%K ESR aminobenzene;redn anion;ionization bisphosphinobenzene;spin charge coupling distribution phosphinoaminobenzene phosphinoaminobenzene;ESR phosphinoaminobenzene;photoelectron phosphinobenzene potential radical spectra
%N 12
%P 3843--3856
%T Photoelectron spectra and molecular properties. 77. Radical ions, XXIII. R2P and R2N substituted benzenes: Charge distribution in their cations, anions, and trianions
%V 111
%X The photoelectron spectra of C6H4(PMe2)2-p (I) and its mono- and diamino analogs and the high-resoln. ESR spectra of their radical ions confirm the different acceptor or donor effects of the 2 substituents and yield information on charge distribution in the mol. states of the individual radical ions. I could be selectively reduced to the radical anion or trianion, but could not be oxidized to the radical cation. on SciFinder(R)
@article{Kaim.1978c,
abstract = {The photoelectron spectra of C6H4(PMe2)2-p (I) and its mono- and diamino analogs and the high-resoln. ESR spectra of their radical ions confirm the different acceptor or donor effects of the 2 substituents and yield information on charge distribution in the mol. states of the individual radical ions. I could be selectively reduced to the radical anion or trianion, but could not be oxidized to the radical cation. [on SciFinder(R)]},
added-at = {2022-06-15T11:26:56.000+0200},
author = {Kaim, Wolfgang and Bock, Hans.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/27ac3340eec7d5f70866864d5d820c25c/huebleriac},
interhash = {c0c9908f8c77a558d0d3f657ff15e8fc},
intrahash = {7ac3340eec7d5f70866864d5d820c25c},
issn = {0009-2940},
journal = {Chemische Berichte},
keywords = {ESR aminobenzene;redn anion;ionization bisphosphinobenzene;spin charge coupling distribution phosphinoaminobenzene phosphinoaminobenzene;ESR phosphinoaminobenzene;photoelectron phosphinobenzene potential radical spectra},
number = 12,
pages = {3843--3856},
timestamp = {2022-06-15T09:26:56.000+0200},
title = {Photoelectron spectra and molecular properties. 77. Radical ions, XXIII. R2P and R2N substituted benzenes: Charge distribution in their cations, anions, and trianions},
volume = 111,
year = 1978
}