Article,

Photoelectron spectra and molecular properties. 77. Radical ions, XXIII. R2P and R2N substituted benzenes: Charge distribution in their cations, anions, and trianions

, and .
Chemische Berichte, 111 (12): 3843--3856 (1978)

Abstract

The photoelectron spectra of C6H4(PMe2)2-p (I) and its mono- and diamino analogs and the high-resoln. ESR spectra of their radical ions confirm the different acceptor or donor effects of the 2 substituents and yield information on charge distribution in the mol. states of the individual radical ions. I could be selectively reduced to the radical anion or trianion, but could not be oxidized to the radical cation. on SciFinder(R)

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