Coordination chemistry of reduced nitrogen heterocycles. Dinuclear pentacarbonyl complexes of molybdenum and tungsten with paramagnetic bridging ligands
W. Kaim. Chemische Berichte, 115 (3):
910--918(1982)
Zusammenfassung
L[M(CO)5]2- (M = Mo, W; L = pyrazine, 2,5-dimethylpyrazine, quinoxaline, phenazine, 4,4'-bipyridine, (E)-1,2-di-4-pyridylethene) were prepd. by reaction of M(CO)6 with the radical anions of the heterocycles L in THF or dimethoxyethane. The metal carbonyl coordination was established by high resoln. ESR which also provided data on the spin distribution and on the conformation of the radical complexes. [on SciFinder(R)]
%0 Journal Article
%1 Kaim.1982e
%A Kaim, Wolfgang.
%D 1982
%J Chemische Berichte
%K binuclear bipyridine carbonyl complex complex;carbonyl complex;molybdenum complex;pyrazine complex;quinoxaline complex;tungsten heterocycle heterocycle;dipyridylethene heterocycle;phenazine molybdenum nitrogen tungsten
%N 3
%P 910--918
%T Coordination chemistry of reduced nitrogen heterocycles. Dinuclear pentacarbonyl complexes of molybdenum and tungsten with paramagnetic bridging ligands
%V 115
%X L[M(CO)5]2- (M = Mo, W; L = pyrazine, 2,5-dimethylpyrazine, quinoxaline, phenazine, 4,4'-bipyridine, (E)-1,2-di-4-pyridylethene) were prepd. by reaction of M(CO)6 with the radical anions of the heterocycles L in THF or dimethoxyethane. The metal carbonyl coordination was established by high resoln. ESR which also provided data on the spin distribution and on the conformation of the radical complexes. [on SciFinder(R)]
@article{Kaim.1982e,
abstract = {L[M(CO)5]2- (M = Mo, W; L = pyrazine, 2,5-dimethylpyrazine, quinoxaline, phenazine, 4,4'-bipyridine, (E)-1,2-di-4-pyridylethene) were prepd. by reaction of M(CO)6 with the radical anions of the heterocycles L in THF or dimethoxyethane. The metal carbonyl coordination was established by high resoln. ESR which also provided data on the spin distribution and on the conformation of the radical complexes. [on SciFinder(R)]},
added-at = {2022-06-15T11:26:56.000+0200},
author = {Kaim, Wolfgang.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/22f0d0147d4e2159f97c78c032964ce27/huebleriac},
interhash = {0785748fa5efd399aa907c27c01e83ad},
intrahash = {2f0d0147d4e2159f97c78c032964ce27},
issn = {0009-2940},
journal = {Chemische Berichte},
keywords = {binuclear bipyridine carbonyl complex complex;carbonyl complex;molybdenum complex;pyrazine complex;quinoxaline complex;tungsten heterocycle heterocycle;dipyridylethene heterocycle;phenazine molybdenum nitrogen tungsten},
number = 3,
pages = {910--918},
timestamp = {2022-06-15T09:26:56.000+0200},
title = {Coordination chemistry of reduced nitrogen heterocycles. Dinuclear pentacarbonyl complexes of molybdenum and tungsten with paramagnetic bridging ligands},
volume = 115,
year = 1982
}
