%0 Journal Article %1 Kaim.1982e %A Kaim, Wolfgang. %D 1982 %J Chemische Berichte %K binuclear bipyridine carbonyl complex complex;carbonyl complex;molybdenum complex;pyrazine complex;quinoxaline complex;tungsten heterocycle heterocycle;dipyridylethene heterocycle;phenazine molybdenum nitrogen tungsten %N 3 %P 910--918 %T Coordination chemistry of reduced nitrogen heterocycles. Dinuclear pentacarbonyl complexes of molybdenum and tungsten with paramagnetic bridging ligands %V 115 %X L[M(CO)5]2- (M = Mo, W; L = pyrazine, 2,5-dimethylpyrazine, quinoxaline, phenazine, 4,4'-bipyridine, (E)-1,2-di-4-pyridylethene) were prepd. by reaction of M(CO)6 with the radical anions of the heterocycles L in THF or dimethoxyethane. The metal carbonyl coordination was established by high resoln. ESR which also provided data on the spin distribution and on the conformation of the radical complexes. [on SciFinder(R)]

@article{Kaim.1982e, abstract = {L[M(CO)5]2- (M = Mo, W; L = pyrazine, 2,5-dimethylpyrazine, quinoxaline, phenazine, 4,4'-bipyridine, (E)-1,2-di-4-pyridylethene) were prepd. by reaction of M(CO)6 with the radical anions of the heterocycles L in THF or dimethoxyethane. The metal carbonyl coordination was established by high resoln. ESR which also provided data on the spin distribution and on the conformation of the radical complexes. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Kaim, Wolfgang.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/22f0d0147d4e2159f97c78c032964ce27/huebleriac}, interhash = {0785748fa5efd399aa907c27c01e83ad}, intrahash = {2f0d0147d4e2159f97c78c032964ce27}, issn = {0009-2940}, journal = {Chemische Berichte}, keywords = {binuclear bipyridine carbonyl complex complex;carbonyl complex;molybdenum complex;pyrazine complex;quinoxaline complex;tungsten heterocycle heterocycle;dipyridylethene heterocycle;phenazine molybdenum nitrogen tungsten}, number = 3, pages = {910--918}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Coordination chemistry of reduced nitrogen heterocycles. Dinuclear pentacarbonyl complexes of molybdenum and tungsten with paramagnetic bridging ligands}, volume = 115, year = 1982 }