Mo(PBu3)2(CO)2(bpm) (bpm = 4,4'-bipyrimidine), Mo(CO)4L (L = 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine, azo-2,2'-bipyridine), and Mo2(CO)8L with very long wavelength change-transfer absorptions (l = 700-1000 nm) were obtained via lowering of the complex LUMO, viz. by using strongly p-accepting a-diimine ligands, and via raising of the metal highest occupied MO, viz. by using the electron-rich metal fragment Mo(PBu3)2(CO)2. The electronic structures of these compds. were studied by electron and IR spectroscopy, by cyclic voltammetry and by ESR of the anion radicals. [on SciFinder(R)]
%0 Journal Article
%1 Kaim.1986b
%A Kaim, Wolfgang
%A Ernst, Sylvia
%A Kohlmann, Stephan.
%D 1986
%J Polyhedron
%K IR IR;bipyrimidine IR;charge IR;molybdenum absorption absorption;pyridyltetrazine azobipyridine carbonyl complex diimine;diimine molybdenum transfer
%N 1-2
%P 445--449
%R 10.1016/S0277-5387(00)84948-7
%T Mono- and binuclear molybdenum carbonyl complexes with charge-transfer absorptions in the near IR
%V 5
%X Mo(PBu3)2(CO)2(bpm) (bpm = 4,4'-bipyrimidine), Mo(CO)4L (L = 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine, azo-2,2'-bipyridine), and Mo2(CO)8L with very long wavelength change-transfer absorptions (l = 700-1000 nm) were obtained via lowering of the complex LUMO, viz. by using strongly p-accepting a-diimine ligands, and via raising of the metal highest occupied MO, viz. by using the electron-rich metal fragment Mo(PBu3)2(CO)2. The electronic structures of these compds. were studied by electron and IR spectroscopy, by cyclic voltammetry and by ESR of the anion radicals. [on SciFinder(R)]
@article{Kaim.1986b,
abstract = {Mo(PBu3)2(CO)2(bpm) (bpm = 4,4'-bipyrimidine), Mo(CO)4L (L = 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine, azo-2,2'-bipyridine), and Mo2(CO)8L with very long wavelength change-transfer absorptions (\textgreek{l} = 700-1000 nm) were obtained via lowering of the complex LUMO, viz. by using strongly \textgreek{p}-accepting \textgreek{a}-diimine ligands, and via raising of the metal highest occupied MO, viz. by using the electron-rich metal fragment Mo(PBu3)2(CO)2. The electronic structures of these compds. were studied by electron and IR spectroscopy, by cyclic voltammetry and by ESR of the anion radicals. [on SciFinder(R)]},
added-at = {2022-06-15T11:26:56.000+0200},
author = {Kaim, Wolfgang and Ernst, Sylvia and Kohlmann, Stephan.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/217afc90e24cc02a5d1ecba7b6da4deb0/huebleriac},
doi = {10.1016/S0277-5387(00)84948-7},
interhash = {9299a5f60440d6d8993d5c2562bdd552},
intrahash = {17afc90e24cc02a5d1ecba7b6da4deb0},
issn = {0277-5387},
journal = {Polyhedron},
keywords = {IR IR;bipyrimidine IR;charge IR;molybdenum absorption absorption;pyridyltetrazine azobipyridine carbonyl complex diimine;diimine molybdenum transfer},
number = {1-2},
pages = {445--449},
timestamp = {2022-06-15T09:26:56.000+0200},
title = {Mono- and binuclear molybdenum carbonyl complexes with charge-transfer absorptions in the near IR},
volume = 5,
year = 1986
}
