%0 Journal Article %1 Kaim.1986b %A Kaim, Wolfgang %A Ernst, Sylvia %A Kohlmann, Stephan. %D 1986 %J Polyhedron %K IR IR;bipyrimidine IR;charge IR;molybdenum absorption absorption;pyridyltetrazine azobipyridine carbonyl complex diimine;diimine molybdenum transfer %N 1-2 %P 445--449 %R 10.1016/S0277-5387(00)84948-7 %T Mono- and binuclear molybdenum carbonyl complexes with charge-transfer absorptions in the near IR %V 5 %X Mo(PBu3)2(CO)2(bpm) (bpm = 4,4'-bipyrimidine), Mo(CO)4L (L = 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine, azo-2,2'-bipyridine), and Mo2(CO)8L with very long wavelength change-transfer absorptions (l = 700-1000 nm) were obtained via lowering of the complex LUMO, viz. by using strongly p-accepting a-diimine ligands, and via raising of the metal highest occupied MO, viz. by using the electron-rich metal fragment Mo(PBu3)2(CO)2. The electronic structures of these compds. were studied by electron and IR spectroscopy, by cyclic voltammetry and by ESR of the anion radicals. on SciFinder(R)

@article{Kaim.1986b, abstract = {Mo(PBu3)2(CO)2(bpm) (bpm = 4,4'-bipyrimidine), Mo(CO)4L (L = 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine, azo-2,2'-bipyridine), and Mo2(CO)8L with very long wavelength change-transfer absorptions (\textgreek{l} = 700-1000 nm) were obtained via lowering of the complex LUMO, viz. by using strongly \textgreek{p}-accepting \textgreek{a}-diimine ligands, and via raising of the metal highest occupied MO, viz. by using the electron-rich metal fragment Mo(PBu3)2(CO)2. The electronic structures of these compds. were studied by electron and IR spectroscopy, by cyclic voltammetry and by ESR of the anion radicals. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Kaim, Wolfgang and Ernst, Sylvia and Kohlmann, Stephan.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/217afc90e24cc02a5d1ecba7b6da4deb0/huebleriac}, doi = {10.1016/S0277-5387(00)84948-7}, interhash = {9299a5f60440d6d8993d5c2562bdd552}, intrahash = {17afc90e24cc02a5d1ecba7b6da4deb0}, issn = {0277-5387}, journal = {Polyhedron}, keywords = {IR IR;bipyrimidine IR;charge IR;molybdenum absorption absorption;pyridyltetrazine azobipyridine carbonyl complex diimine;diimine molybdenum transfer}, number = {1-2}, pages = {445--449}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Mono- and binuclear molybdenum carbonyl complexes with charge-transfer absorptions in the near IR}, volume = 5, year = 1986 }