A review. This review touches the most common instances where noninnocent (suspect) behavior of redox-active ligands, either substrates or supporting components, is obsd. in a biochem. context. These ligands include the O2/O2·-/O22-, NO+/NO·/NO-, o-quinone/o-semiquinone/catecholate and tyrosyl/tyrosinate redox systems, the tetrapyrrole (porphyrinic) ligands, the pterins and flavins, and the dithiolene/ene-dithiolate ligands in molybdo- and tungstopterin. These noninnocent ligands are discussed in their interaction with biol. iron, copper, manganese, molybdenum or tungsten centers. on SciFinder(R)
%0 Journal Article
%1 Kaim.2010b
%A Kaim, Wolfgang
%A Schwederski, Brigitte.
%D 2010
%J Coordination Chemistry Reviews
%K active ligand metal noninnocent prepn redox review transition
%N 13-14
%P 1580--1588
%R 10.1016/j.ccr.2010.01.009
%T Non-innocent ligands in bioinorganic chemistry: An overview
%V 254
%X A review. This review touches the most common instances where noninnocent (suspect) behavior of redox-active ligands, either substrates or supporting components, is obsd. in a biochem. context. These ligands include the O2/O2·-/O22-, NO+/NO·/NO-, o-quinone/o-semiquinone/catecholate and tyrosyl/tyrosinate redox systems, the tetrapyrrole (porphyrinic) ligands, the pterins and flavins, and the dithiolene/ene-dithiolate ligands in molybdo- and tungstopterin. These noninnocent ligands are discussed in their interaction with biol. iron, copper, manganese, molybdenum or tungsten centers. on SciFinder(R)
@article{Kaim.2010b,
abstract = {A review. This review touches the most common instances where noninnocent (suspect) behavior of redox-active ligands, either substrates or supporting components, is obsd. in a biochem. context. These ligands include the O2/O2·-/O22-, NO+/NO·/NO-, o-quinone/o-semiquinone/catecholate and tyrosyl/tyrosinate redox systems, the tetrapyrrole (porphyrinic) ligands, the pterins and flavins, and the dithiolene/ene-dithiolate ligands in molybdo- and tungstopterin. These noninnocent ligands are discussed in their interaction with biol. iron, copper, manganese, molybdenum or tungsten centers. [on SciFinder(R)]},
added-at = {2022-06-15T11:26:56.000+0200},
author = {Kaim, Wolfgang and Schwederski, Brigitte.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2b4bb822d6bd34eaf40e7af0634e9a0cd/huebleriac},
doi = {10.1016/j.ccr.2010.01.009},
interhash = {8ab3630c5197b6fab0938872e08c6fc6},
intrahash = {b4bb822d6bd34eaf40e7af0634e9a0cd},
issn = {0010-8545},
journal = {Coordination Chemistry Reviews},
keywords = {active ligand metal noninnocent prepn redox review transition},
number = {13-14},
pages = {1580--1588},
timestamp = {2022-06-15T09:26:56.000+0200},
title = {Non-innocent ligands in bioinorganic chemistry: An overview},
volume = 254,
year = 2010
}
