%0 Journal Article %1 Su.2002 %A Su, Cheng-Yong %A Cai, Yue-Peng %A Chen, Chun-Long %A Lissner, Falk %A Kang, Bei-Sheng %A Kaim, Wolfgang. %D 2002 %J Angewandte Chemie, International Edition %K anion benzimidazolylmethylbenzene copper encapsulating fluoroborate ligand metallocage prepn prepn;copper prepn;silver silver tridentate trisbenzimidazolylmethylbenzene %N 18 %P 3371--3375 %R 10.1002/1521-3773(20020916)41:18\textless3371::AID-ANIE3371\textgreater3.0.CO;2-4 %T Self-assembly of trigonal-prismatic metallocages encapsulating BF4- or CuI32- as anionic guests: Structures and mechanism of formation %V 41 %X Thermodynamically stable, but kinetically labile trigonal-prismatic M3L2 metallocages occur in [BF4 $\subset$ Ag3(MsTBim)2](BF4)2 (1) and [CuI3 ⊂ [Cu3(MsTBim)2]2](Cu2I4) (2), the latter with an unprecedented metal-complex-host/metal-complex-guest arrangement. Large anions such as CF3SO3- or BPh4- have to reside outside the cage facing its windows. MsTBim = 1,3,5-tris-(benzimidazol-1-ylmethyl)-2,4,6-trimethylbenzene. [on SciFinder(R)]

@article{Su.2002, abstract = {Thermodynamically stable, but kinetically labile trigonal-prismatic M3L2 metallocages occur in [BF4 $\subset$ {Ag3(MsTBim)2}](BF4)2 (1) and [{CuI3 ⊂ [Cu3(MsTBim)2]}2](Cu2I4) (2), the latter with an unprecedented metal-complex-host/metal-complex-guest arrangement. Large anions such as CF3SO3- or BPh4- have to reside outside the cage facing its windows. MsTBim = 1,3,5-tris-(benzimidazol-1-ylmethyl)-2,4,6-trimethylbenzene. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Su, Cheng-Yong and Cai, Yue-Peng and Chen, Chun-Long and Lissner, Falk and Kang, Bei-Sheng and Kaim, Wolfgang.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/26e3c48c84b71330a58b3263518d4def8/huebleriac}, doi = {10.1002/1521-3773(20020916)41:18{\textless}3371::AID-ANIE3371{\textgreater}3.0.CO;2-4}, interhash = {584cda7c090f7e44614c6a77135d0edb}, intrahash = {6e3c48c84b71330a58b3263518d4def8}, issn = {1433-7851}, journal = {Angewandte Chemie, International Edition}, keywords = {anion benzimidazolylmethylbenzene copper encapsulating fluoroborate ligand metallocage prepn prepn;copper prepn;silver silver tridentate trisbenzimidazolylmethylbenzene}, number = 18, pages = {3371--3375}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Self-assembly of trigonal-prismatic metallocages encapsulating BF4- or CuI32- as anionic guests: Structures and mechanism of formation}, volume = 41, year = 2002 }