Thermodynamically stable, but kinetically labile trigonal-prismatic M3L2 metallocages occur in BF4 $\subset$ Ag3(MsTBim)2(BF4)2 (1) and CuI3 ⊂ Cu3(MsTBim)22(Cu2I4) (2), the latter with an unprecedented metal-complex-host/metal-complex-guest arrangement. Large anions such as CF3SO3- or BPh4- have to reside outside the cage facing its windows. MsTBim = 1,3,5-tris-(benzimidazol-1-ylmethyl)-2,4,6-trimethylbenzene. on SciFinder(R)
%0 Journal Article
%1 Su.2002
%A Su, Cheng-Yong
%A Cai, Yue-Peng
%A Chen, Chun-Long
%A Lissner, Falk
%A Kang, Bei-Sheng
%A Kaim, Wolfgang.
%D 2002
%J Angewandte Chemie, International Edition
%K anion benzimidazolylmethylbenzene copper encapsulating fluoroborate ligand metallocage prepn prepn;copper prepn;silver silver tridentate trisbenzimidazolylmethylbenzene
%N 18
%P 3371--3375
%R 10.1002/1521-3773(20020916)41:18\textless3371::AID-ANIE3371\textgreater3.0.CO;2-4
%T Self-assembly of trigonal-prismatic metallocages encapsulating BF4- or CuI32- as anionic guests: Structures and mechanism of formation
%V 41
%X Thermodynamically stable, but kinetically labile trigonal-prismatic M3L2 metallocages occur in BF4 $\subset$ Ag3(MsTBim)2(BF4)2 (1) and CuI3 ⊂ Cu3(MsTBim)22(Cu2I4) (2), the latter with an unprecedented metal-complex-host/metal-complex-guest arrangement. Large anions such as CF3SO3- or BPh4- have to reside outside the cage facing its windows. MsTBim = 1,3,5-tris-(benzimidazol-1-ylmethyl)-2,4,6-trimethylbenzene. on SciFinder(R)
@article{Su.2002,
abstract = {Thermodynamically stable, but kinetically labile trigonal-prismatic M3L2 metallocages occur in [BF4 $\subset$ {Ag3(MsTBim)2}](BF4)2 (1) and [{CuI3 ⊂ [Cu3(MsTBim)2]}2](Cu2I4) (2), the latter with an unprecedented metal-complex-host/metal-complex-guest arrangement. Large anions such as CF3SO3- or BPh4- have to reside outside the cage facing its windows. MsTBim = 1,3,5-tris-(benzimidazol-1-ylmethyl)-2,4,6-trimethylbenzene. [on SciFinder(R)]},
added-at = {2019-07-15T13:41:23.000+0200},
author = {Su, Cheng-Yong and Cai, Yue-Peng and Chen, Chun-Long and Lissner, Falk and Kang, Bei-Sheng and Kaim, Wolfgang.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/26e3c48c84b71330a58b3263518d4def8/b_schwederski},
doi = {10.1002/1521-3773(20020916)41:18{\textless}3371::AID-ANIE3371{\textgreater}3.0.CO;2-4},
interhash = {584cda7c090f7e44614c6a77135d0edb},
intrahash = {6e3c48c84b71330a58b3263518d4def8},
issn = {1433-7851},
journal = {Angewandte Chemie, International Edition},
keywords = {anion benzimidazolylmethylbenzene copper encapsulating fluoroborate ligand metallocage prepn prepn;copper prepn;silver silver tridentate trisbenzimidazolylmethylbenzene},
number = 18,
pages = {3371--3375},
timestamp = {2019-07-15T11:42:10.000+0200},
title = {Self-assembly of trigonal-prismatic metallocages encapsulating BF4- or CuI32- as anionic guests: Structures and mechanism of formation},
volume = 41,
year = 2002
}