Charge and electron transfer from metal-to-carbon bonds of Main Group organometallics MRn (M = Al, Ga, Zn) to aromatic N-heterocycles: Colored precursor compounds and radical complex formation. Inorganica Chimica Acta, (225)1-2:23--34, 1994. [PUMA: Group aluminum bond carbon charge gallium metal organometallic organometallic;Main organometallic;heterocycle reaction transfer zinc]
Coordinative aspects of single electron exchange between Main group or transition metal compounds and unsaturated organic substrates. Studies in Physical and Theoretical Chemistry, (78)Electron Proton Transfer Chem. Biol:45--69, 1992. [PUMA: Main electron exchange exchange;transition group metal organo review review;review single]
Edge-sharing of two five-membered metal chelate rings; structures and magnetism of molybdenum(0)-, copper(I)-, and cobalt(II)-complexes with the S-frame ligand azo-2,2'-pyridine. Zeitschrift fuer Anorganische und Allgemeine Chemie, (598-599):217--234, 1991. [PUMA: azopyridine cobalt complex complex;transition copper magnetic metal molybdenum prepn property;crystal structure]
Complexes of the imine/thioether mixed-donor ligand 8-methylthioquinoline with d6-configurated transition metal centers: Synthesis, structures and comparison with complexes of 1-methyl-2-(methylthiomethyl)-1H-benzimidazole. Inorganica Chimica Acta, (357)11:3325--3330, 2004. [PUMA: bipyridine complex complex;ruthenium crystal electrochem metal methylthiomethylbenzimidazole methylthioquinoline prepn redox redox;transition structure transition]
Chemistry: Odd electron on nitrogen: A metal-stabilized aminyl radical. Science (Washington, DC, United States), (307)5707:216--217, 2005. [PUMA: aminyl biochem electron metal nitrogen odd prepn radical review;review stabilized]
RuII(a-diimine) or RuIII(a-diimine·-)? Structural, Spectroscopic, and Theoretical Evidence for the Stabilization of a Prominent Metal-to-Ligand Charge-Transfer Excited-State Configuration in the Ground State. European Journal of Inorganic Chemistry, (2014)1:110--119, 2014. [PUMA: ESR acetylacetonato alpha charge complex configuration crystal diazabutadiene excited ground ligand metal mol pentanedionate prepn radical ruthenium spectroelectrochem;diimine state structure;stabilization transfer]
Storage and liberation of molecular hydrogen by ligand-stabilized metal centers: Energietraeger Wasserst., Jahreskolloq. Sonderforschungsbereichs 270 Univ. Stuttgart. In W. Bruns, W. Kaim, M. Ladwig, W. Matheis, and T. Roth (Eds.), VDI-Verlag, 1991. [PUMA: addn complex hydrogen metal review transition]
Triple-decker sandwich complexes with cyclo-P6 as middle deck. Chemische Berichte, (121)3:443--449, 1988. [PUMA: complex;triple complex;tungsten crystal cyclophosphorus decker hexaphosphacyclohexane metal sandwich sandwich;mol structure structure;vanadium tungsten vanadium;redox]
Manifestations of Noninnocent Ligand Behavior. Inorganic Chemistry, (50)20:9752--9765, 2011. [PUMA: active complex ligand metal noninnocent redox review transition]
Ground state electron transfer between TCNE and one or more 16-electron species containing vanadium, osmium, ruthenium or cobalt. Inorganica Chimica Acta, (251)1-2:239--248, 1996. [PUMA: TCNE UV cobalt complex;IR complex;electron complex;magnetic complex;osmium electron ground metal property state transfer transfer;electrochem transfer;ruthenium transfer;vanadium]
Singlet Diradical Complexes of Chromium, Molybdenum, and Tungsten with Azo Anion Radical Ligands from M(CO)6 Precursors. Inorganic Chemistry, (46)21:8584--8593, 2007. [PUMA: 6 Group arylamidophenylazopyridine crystal diradical diradical;Group diradical;electronic electrochem metal prepn redox singlet structure]
Homo- and heterodinuclear complexes of D2h-symmetric bis(chelate) ligand 2,2'-bipyrimidine with electron-rich metal fragments Mo(CO)4, Re(CO)3Cl, [Cu(PPh3)2]+, and [Ru(bpy)2]2+. Zeitschrift fuer Anorganische und Allgemeine Chemie, (593):147--159, 1991. [PUMA: bipyridine bipyrimidine carbonyl copper dinuclear;molybdenum dinuclear;redn dinuclear;rhenium electrochem heterodinuclear heterodinuclear;electrochem heterodinuclear;oxidn heterodinuclear;ruthenium heterodinuclear;solvatochromism homodinuclear metal phosphine redox transition]
Chemistry of C-Trimethylsilyl-Substituted Heterocarboranes. 28. Selective Alkylation and Reactivity of \dqCarbons Adjacent\dq and \dqCarbons Apart\dq Tetracarba-nido-dodecaborane(12) Derivatives toward Group 1 and Group 2 Metals. Synthetic, Spectroscopic, and Structural Investigations on Lithium-, Sodium-, Potassium-, Cesium-, and Magnesium-Complexed C4B8 Carboranes. Organometallics, (19)4:497--508, 2000. [PUMA: DFT Group IA alkylation;magnesacarborane calcn calcn;mol crystal geometry magnesacarborane;heterocarborane magnesium metal metalation metallacarborane optimized prepn structure substituted substituted;DFT trimethylsilyl]
Singlet Diradical Complexes of Ruthenium and Osmium: Geometrical and Electronic Structures and their Unexpected Changes on Oxidation. Inorganic Chemistry, (47)5:1625--1633, 2008. [PUMA: 8 ESR UV crystal diradical electrochem metal osmium oxidn phenylaminophenylazopyridine phenylaminophenylazopyridine;group prepn ruthenium singlet spectroelectrochem;phenylaminophenylazopyridine structure]
The shortest metal-metal bond yet: Molecular and electronic structure of a dinuclear chromium diazadiene complex. Chemtracts, (20)7:292--296, 2007. [PUMA: bond chromium complex diazadiene metal review shortest]
Electron transfer induced metal addition and ligand exchange in organometallic anion radical complexes. NATO ASI Series, Series C: Mathematical and Physical Sciences, (257)Paramagn. Organomet. Species Act./Sel., Catal:283--294, 1989. [PUMA: anion complex electron formation metal reaction review;polynuclear review;review transfer transition]
Cooperation of metals with electroactive ligands of biochemical relevance: Beyond metalloporphyrins. Pure and Applied Chemistry, (76)2:351--364, 2004. [PUMA: amine electroactive ligand metal oxidase oxotransferase review transition]
The p* Molecular Orbital Crossing a2(q)/b1(y) in 1,10-Phenanthroline Derivatives. Ab Initio Calculations and EPR/ENDOR Studies of the 4,7-Diaza-1,10-phenanthroline Radical Anion and Its M(CO)4 Complexes (M = Cr, Mo, W). Inorganic Chemistry, (35)5:1295--1300, 1996. [PUMA: EPR MO ab carbonyl chromium complex crossing deriv deriv;MO diazaphenanthroline initio initio;ENDOR initio;diazaphenanthroline initio;molybdenum initio;tungsten metal phenanthroline]
Spectroelectrochemistry of aromatic ligands and their derivatives. III. Binuclear transition metal complexes of copper(I), molybdenum(0), and rhenium(I) with 2,2'-bipyrimidine. [Erratum to document cited in CA116(2):12392f]. Journal of Organometallic Chemistry, (424)1:C2, 1992. [PUMA: Erratum Erratum;Erratum bipyrimidine carbonyl complex copper electronic electroredn metal potential;molybdenum redn rhenium spectrum transition visible]
The reduction behavior of pentacarbonylpyridinechromium, -molybdenum and -tungsten complexes. Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, (39B)6:801--807, 1984. [PUMA: coordination deriv effect electrochem heterocyclic iodomethylate ligand metal pyridine redn;pentacarbonyl redn;substituent transition]
Stabilization of biochemically interesting intermediates by metal coordination. 5. Complexes of zinc, copper(I), rhenium(I), and ruthenium(II) with singly reduced 2,5-diacetylpyrazine. Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, (85)12:4075--4082, 1989. [PUMA: ESR anion chelate complex;diacetylpyrazine coordination copper metal metal;redox radical reaction rhenium ruthenium zinc]
Correlation between solvatochromism and back-bonding in four isomeric (a-diimine)M(CO)4 complexes (M = Cr, Mo, W). Journal of Organometallic Chemistry, (302)2:211--215, 1986. [PUMA: backbonding backbonding;bipyrimidine backbonding;biyridazine backbonding;chromium backbonding;molybdenum backbonding;tungsten bipyrazine complex diimine metal solvatochromism]
Unexpected paramagnetism of mono- and polynuclear 18 valence electron metal carbonyl complexes [(CnRn)(CO)2M]k(L), M = chromium, manganese; k = 1, 2, 4. Implications for photoreactivity. Journal of the American Chemical Society, (114)14:5693--5697, 1992. [PUMA: carbonyl chromium complex complex;susceptibility metal paramagnetic susceptibility;manganese susceptibility;paramagnetism transition]
2,5-Bis(1-phenyliminoethyl)pyrazine (bpip): A conjugated metal-metal bridging acceptor ligand and its homodinuclear complexes with low-valent metal centers. Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry, 4:575--582, 1999. [PUMA: complex complex;electrochem complex;iminoethylpyrazine complex;spectroelectrochem complex;transition copper crystal data dinuclear iminoethylpyrazine ligand metal prepn reduced structure structure;solvatochromism transition]
Poly(L-lysine) as a polychelatogen to remove toxic metals using ultrafiltration and bactericide properties of poly(L-lysine)-Cu2+ complexes. Polymer Bulletin (Heidelberg, Germany), (67)5:763--774, 2011. [PUMA: Escherichia L Staphylococcus copper lysine metal poly toxic ultrafiltration]
Mono- and binuclear pentacarbonyl complexes of chromium, molybdenum and tungsten with the anion radicals of 2,1,3-benzoxadiazole, 2,1,3-benzothiadiazole and 2,1,3-benzoselenadiazole. Journal of Organometallic Chemistry, (264)3:317--326, 1984. [PUMA: ESR;benzoselenadiazole ESR;benzothiadiazole ESR;benzoxadiazole ESR;diazole benzochalcogenadiazole complex metal radical]
The d0, d1, and d2 Configurations in Known and Unknown Tetrathiometal Compounds MS4n- (M = Mo, Tc, Ru; W, Re, Os). A Quantum Chemical Study. Inorganic Chemistry, (38)26:6101--6105, 1999. [PUMA: calcn calcn;molybdenum calcn;osmium calcn;rhenium calcn;ruthenium calcn;technetium calcn;tetrathiometalate calcn;thiometalate calcn;transition calcn;tungsten electronic energetic metal metalate mol structure sulfide tetrathio]
Binuclear radical complexes of heavy-metal fragments containing ruthenium, osmium, rhodium and gold. Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, (85)12:4047--4052, 1989. [PUMA: ESR ESR;osmium ESR;rhodium bipyridine complex complex;gold metal norbornadiene phosphine pyridyltetrazine radical transition]
Non-innocent ligands in bioinorganic chemistry: An overview. Coordination Chemistry Reviews, (254)13-14:1580--1588, 2010. [PUMA: active ligand metal noninnocent prepn redox review transition]
Electron transfer catalyzed substitution in carbonyl complexes. IV. Mononuclear s- and p-coordinated complexes of manganese, chromium and tungsten with tetracyanoethylene and tetracyano-p-quinodimethane. Journal of Organometallic Chemistry, (366)1-2:155--174, 1989. [PUMA: IR TCNQ chromium complex;TCNE elec manganese mechanism metal metal;substitution potential redox solvate tetracyanoethene tungsten]
Paramagnetic main Group and transition metal complexes containing unsaturated nitrogen ligands. Journal of Organometallic Chemistry Library, (22)Organomet. Radical Processes:173--200, 1990. [PUMA: Group complex ligand main metal nitrogen paramagnetic review review;paramagnetic transition]
Electrochemical, spectroscopic and EPR study of transition metal complexes of dipyrido[3,2-a:2',3'-c]phenazine. Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry, 15:2595--2600, 1999. [PUMA: EPR absorption complex complex;cyclic complex;electrochem complex;electroredn dipyridophenazine metal spectra spectroscopic study transition voltammetry]
Stabilization of biochemically interesting intermediates by metal coordination. 6. Charge transfer in complexes of 1,3-dimethyllumazine with low-valent metals. Inorganic Chemistry, (28)26:4645--4648, 1989. [PUMA: charge complex complex;electrochem complex;ruthenium complex;transition lumazine lumazine;copper lumazine;rhenium metal redox transfer transition]
Coordination chemistry of reduced N-heterocycles. Complexes of pyrazine anion radical with phenyl metal cations +MPh of beryllium, magnesium and zinc. Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, (36B)9:1110--1116, 1981. [PUMA: anion beryllium complex complex;ESR complex;magnesium complex;pyrazine complex;zinc metal pyrazine radical]
Coordination compounds of reduced pyrazine with alkyl derivatives of boron, aluminum, gallium, and indium. Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, (36B)6:677--682, 1981. [PUMA: aluminum complex metal pyrazine radical complex;boron complex;gallium complex;indium complex;pyrazine]
Homologous chromium, molybdenum, and tungsten derivatives of 6-chloro-2-hydroxypyridine. Inductive effects on the metal-metal bond length. Inorganic Chemistry, (19)6:1453--1457, 1980. [PUMA: binuclear binuclear;tungsten bond bond;inductive bond;molybdenum bond;structure chlorohydroxypyridine chromium effect metal transition]
Electronic structure of heterodinuclear complexes (bpy)2RuII(m-bpym)MLn; bpy = 2,2'-bipyridine; bpym = 2,2'-bipyrimidine; MLn = Cu(PPh3)2, Mo(CO)4, Re(CO)3Cl. Inorganica Chimica Acta, (181)1:15--21, 1991. [PUMA: ESR bipyridine bipyrimidine complex complex;copper complex;molybdenum complex;redox complex;ruthenium electrochem heterobinuclear heterobinuclear;rhenium heterodinuclear metal ruthenium transition]
Coordination of rhodium(III), iridium(III), and copper(II) with the potentially tetradentate acceptor ligand bis(1-methylimidazol-2-yl)glyoxal (big). Zeitschrift fuer Anorganische und Allgemeine Chemie, (626)6:1341--1348, 2000. [PUMA: ESR;imidazolylglyoxal complex complex;rhodium coordination;iridium copper crystal imidazolylglyoxal metal prepn rhodium structure structure;mol transition]
From ion pairs to radical complexes: Coordination compounds of reduced 2,2'-bipyridine with organometallic cations. Chemische Berichte, (114)12:3789--3800, 1981. [PUMA: IA IIA bipyridine complex complex;ESR complex;Group complex;radical metal]
Azo compounds as electron acceptor or radical ligands in transition metal species: Spectroelectrochemistry and high-field EPR studies of ruthenium, rhodium and copper complexes of 2,2'-azobis(5-chloropyrimidine). Journal of Molecular Structure, (656)1-3:183--194, 2003. [PUMA: ESR azochloropyrimidine azochloropyrimidine;transition chloroazopyrimidine;electrochem crystal cyclic metal oxidn prepn redn spectroelectrochem structure transition voltammetry]
A series of metal complexes with the non-innocent N,N'-bis(pentafluorophenyl)-o-phenylenediamido ligand: Twisted geometry for tuning the electronic structure. Dalton Transactions, 10:1355--1365, 2008. [PUMA: antiferromagnetic complex complex;crystal complex;cyclic complex;fluorophenylphenylenediamine complexation deriv exchange fluorophenylphenylenediamido metal metal;transition oxidn prepn structure transition voltammetry]
Concepts for metal complex chromophores absorbing in the near infrared. Coordination Chemistry Reviews, (255)21-22:2503--2513, 2011. [PUMA: NIR absorption chromophore complex metal review]
Spectroelectrochemistry of aromatic ligands and their derivatives. III. Binuclear transition metal complexes of copper(I), molybdenum(0), and rhenium(I) with 2,2'-bipyrimidine. Journal of Organometallic Chemistry, (411)1-2:207--213, 1991. [PUMA: binuclear bipyrimidine carbonyl complex copper electronic electroredn;transition metal potential redn rhenium spectrum spectrum;molybdenum visible]
Can geometry control the coordination behaviour of 2-hydroxy-1-naphthaldehyde-N(4)-phenylthiosemicarbazone? A study towards its origin. Inorganica Chimica Acta, (376)1:317--324, 2011. [PUMA: complex complex;cyclic complex;prepn crystal hydroxynaphthaldehyde metal phenylthiosemicarbazone structure transition voltammetry]
The coordination chemistry of 1,2,4,5-tetrazines. Coordination Chemistry Reviews, (230)1-2:127--139, 2002. [PUMA: complex metal review tetrazine transition]
The mpz+/mpz.bul. pair as organic analog of the NO+/NO.bul. ligand redox system (mpz = N-methylpyrazinium). A combined electrochemical and spectroscopic study (UV/Vis/NIR, IR, EPR) of complexes [(mpz)M(CN)5]2-/3- (M = Fe, Ru, Os). Inorganic Chemistry, (36)14:2969--2974, 1997. [PUMA: IR analog;near complex complex;EPR complex;IR complex;iron complex;osmium complex;visible cyano electrochem metal methylpyrazinium nitrosyl pentacyano redn spectra spectroscopy;UV spectroscopy;electrochem spectroscopy;methylpyrazinium spectroscopy;ruthenium]
New saccharinate complexes with 3,3'-azobispyridine ligand: Synthesis, characterization, and spectroscopic properties. Journal of Coordination Chemistry, (70)16:2853--2869, 2017. [PUMA: azobispyridine complex coordination crystal metal polymer polymer;photoluminescence polymer;thermal polymer;transition prepn saccharinate stability structure transition]
The reaction of heterocyclic anion radicals with Group VI carbonyls. ESR characterization of paramagnetic binuclear complexes. Inorganica Chimica Acta, (53)4:L151-L153, 1981. [PUMA: ESR ESR;ESR ESR;carbonyl ESR;tungsten anion anion;molybdenum bipyridine metal pyrazine radical]
Ambidentate ligand with high p-acceptor capacity: D6-metal complexes of 4,4'-bipyrimidine. Angewandte Chemie, (97)5:431--433, 1985. [PUMA: Group VIB bipyridine bipyrimidine bipyrimidine;bipyrimidine bipyrimidine;chromium bipyrimidine;tungsten carbonyl carbonyl;molybdenum carbonyl;redox electrochem metal ruthenium ruthenium;carbonyl transition]
Mixed valency in ruthenium complexes - Coordinative aspects. Coordination Chemistry Reviews, (251)3+4:584--594, 2007. [PUMA: complex interaction metal mixed review ruthenium valence]