Stabilization of biochemically interesting intermediates by metal coordination. 6. Charge transfer in complexes of 1,3-dimethyllumazine with low-valent metals
Chelate complexes between O(4), N(5)-coordinating 1,3-dimethyllumazine and the metal fragments (Ph3P)2Cu+, (bpy)2Ru2+ (bpy = 2,2'-bipyridine), and (OC)3ClRe have metal-to-ligand charge-transfer absorption bands in the visible region. Cyclic voltammetry illustrates the thermodn. and kinetic stabilization of the reduced state in these complexes. The prepns. of the Cu and Ru complexes are given. on SciFinder(R)
%0 Journal Article
%1 Bessenbacher.1989f
%A Bessenbacher, Christian
%A Vogler, Conny
%A Kaim, Wolfgang.
%D 1989
%J Inorganic Chemistry
%K charge complex complex;electrochem complex;ruthenium complex;transition lumazine lumazine;copper lumazine;rhenium metal redox transfer transition
%N 26
%P 4645--4648
%R 10.1021/ic00325a021
%T Stabilization of biochemically interesting intermediates by metal coordination. 6. Charge transfer in complexes of 1,3-dimethyllumazine with low-valent metals
%V 28
%X Chelate complexes between O(4), N(5)-coordinating 1,3-dimethyllumazine and the metal fragments (Ph3P)2Cu+, (bpy)2Ru2+ (bpy = 2,2'-bipyridine), and (OC)3ClRe have metal-to-ligand charge-transfer absorption bands in the visible region. Cyclic voltammetry illustrates the thermodn. and kinetic stabilization of the reduced state in these complexes. The prepns. of the Cu and Ru complexes are given. on SciFinder(R)
@article{Bessenbacher.1989f,
abstract = {Chelate complexes between O(4), N(5)-coordinating 1,3-dimethyllumazine and the metal fragments (Ph3P)2Cu+, (bpy)2Ru2+ (bpy = 2,2'-bipyridine), and (OC)3ClRe have metal-to-ligand charge-transfer absorption bands in the visible region. Cyclic voltammetry illustrates the thermodn. and kinetic stabilization of the reduced state in these complexes. The prepns. of the Cu and Ru complexes are given. [on SciFinder(R)]},
added-at = {2019-07-15T13:41:23.000+0200},
author = {Bessenbacher, Christian and Vogler, Conny and Kaim, Wolfgang.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/20e771ceba9a150dea715a02669db93d9/b_schwederski},
doi = {10.1021/ic00325a021},
interhash = {04165bb680133870e3eba414ae8b5003},
intrahash = {0e771ceba9a150dea715a02669db93d9},
issn = {0020-1669},
journal = {Inorganic Chemistry},
keywords = {charge complex complex;electrochem complex;ruthenium complex;transition lumazine lumazine;copper lumazine;rhenium metal redox transfer transition},
number = 26,
pages = {4645--4648},
timestamp = {2019-07-15T11:42:10.000+0200},
title = {Stabilization of biochemically interesting intermediates by metal coordination. 6. Charge transfer in complexes of 1,3-dimethyllumazine with low-valent metals},
volume = 28,
year = 1989
}