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Stabilization of biochemically interesting intermediates by metal coordination. 6. Charge transfer in complexes of 1,3-dimethyllumazine with low-valent metals

, , und . Inorganic Chemistry 28 (26): 4645--4648 (1989)

Zusammenfassung

Chelate complexes between O(4), N(5)-coordinating 1,3-dimethyllumazine and the metal fragments (Ph3P)2Cu+, (bpy)2Ru2+ (bpy = 2,2'-bipyridine), and (OC)3ClRe have metal-to-ligand charge-transfer absorption bands in the visible region. Cyclic voltammetry illustrates the thermodn. and kinetic stabilization of the reduced state in these complexes. The prepns. of the Cu and Ru complexes are given. on SciFinder(R)

Links und Ressourcen

DOI:
10.1021/ic00325a021
BibTeX-Schlüssel:
Bessenbacher.1989f
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