Coordination compounds of reduced pyrazine with alkyl derivatives of boron, aluminum, gallium, and indium
W. Kaim. Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 36B (6):
677--682(1981)
Abstract
The alkyls MR3 (M = B, Al, Ga, In; R = Me, Et) react with pyrazine and Na in THF to yield persistent radical complexes (I). Use of TlR3 leads to rapid deposition of Tl. The formation of these ionic complexes I is the result of MR3 dissocn. into +MR2 and -MR4 ions. All radicals were identified and characterized by ESR; the data reveal the influence of N-B back bonding in the B deriv. on SciFinder(R)
%0 Journal Article
%1 Kaim.1981d
%A Kaim, Wolfgang.
%D 1981
%J Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie
%K aluminum complex complex;boron complex;gallium complex;indium complex;pyrazine metal pyrazine radical
%N 6
%P 677--682
%T Coordination compounds of reduced pyrazine with alkyl derivatives of boron, aluminum, gallium, and indium
%V 36B
%X The alkyls MR3 (M = B, Al, Ga, In; R = Me, Et) react with pyrazine and Na in THF to yield persistent radical complexes (I). Use of TlR3 leads to rapid deposition of Tl. The formation of these ionic complexes I is the result of MR3 dissocn. into +MR2 and -MR4 ions. All radicals were identified and characterized by ESR; the data reveal the influence of N-B back bonding in the B deriv. on SciFinder(R)
@article{Kaim.1981d,
abstract = {The alkyls MR3 (M = B, Al, Ga, In; R = Me, Et) react with pyrazine and Na in THF to yield persistent radical complexes (I). Use of TlR3 leads to rapid deposition of Tl. The formation of these ionic complexes I is the result of MR3 dissocn. into +MR2 and -MR4 ions. All radicals were identified and characterized by ESR; the data reveal the influence of N-B back bonding in the B deriv. [on SciFinder(R)]},
added-at = {2019-07-15T13:41:23.000+0200},
author = {Kaim, Wolfgang.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/28741e9e78bf52d91e4a92eebb2d24613/b_schwederski},
interhash = {996959beaeaced2311bd6c6cd034b26e},
intrahash = {8741e9e78bf52d91e4a92eebb2d24613},
issn = {0340-5087},
journal = {Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie},
keywords = {aluminum complex complex;boron complex;gallium complex;indium complex;pyrazine metal pyrazine radical},
number = 6,
pages = {677--682},
timestamp = {2019-07-15T11:42:10.000+0200},
title = {Coordination compounds of reduced pyrazine with alkyl derivatives of boron, aluminum, gallium, and indium},
volume = {36B},
year = 1981
}