%0 Journal Article %1 Kaim.1981d %A Kaim, Wolfgang. %D 1981 %J Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie %K aluminum complex complex;boron complex;gallium complex;indium complex;pyrazine metal pyrazine radical %N 6 %P 677--682 %T Coordination compounds of reduced pyrazine with alkyl derivatives of boron, aluminum, gallium, and indium %V 36B %X The alkyls MR3 (M = B, Al, Ga, In; R = Me, Et) react with pyrazine and Na in THF to yield persistent radical complexes (I). Use of TlR3 leads to rapid deposition of Tl. The formation of these ionic complexes I is the result of MR3 dissocn. into +MR2 and -MR4 ions. All radicals were identified and characterized by ESR; the data reveal the influence of N-B back bonding in the B deriv. [on SciFinder(R)]

@article{Kaim.1981d, abstract = {The alkyls MR3 (M = B, Al, Ga, In; R = Me, Et) react with pyrazine and Na in THF to yield persistent radical complexes (I). Use of TlR3 leads to rapid deposition of Tl. The formation of these ionic complexes I is the result of MR3 dissocn. into +MR2 and -MR4 ions. All radicals were identified and characterized by ESR; the data reveal the influence of N-B back bonding in the B deriv. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Kaim, Wolfgang.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/28741e9e78bf52d91e4a92eebb2d24613/huebleriac}, interhash = {996959beaeaced2311bd6c6cd034b26e}, intrahash = {8741e9e78bf52d91e4a92eebb2d24613}, issn = {0340-5087}, journal = {Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie}, keywords = {aluminum complex complex;boron complex;gallium complex;indium complex;pyrazine metal pyrazine radical}, number = 6, pages = {677--682}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Coordination compounds of reduced pyrazine with alkyl derivatives of boron, aluminum, gallium, and indium}, volume = {36B}, year = 1981 }