Publications

Srikanta Patra, Biprajit Sarkar, Sandeep Ghumaan, Jan Fiedler, Stanislav Zalis, Wolfgang Kaim, and Goutam Kumar. Lahiri. (μ-L)RuII(acac)22n, n = 2+, +, 0, -, 2-, with L = 3,3',4,4'-tetraimino-3,3',4,4'-tetrahydrobiphenyl. EPR-supported assignment of NIR absorptions for the paramagnetic intermediates. Dalton Transactions, 5:750--753, 2004. [PUMA: DFT IR MO binuclear calcn;near complex complex;EPR complex;frontier complex;ruthenium electrochem paramagnetic prepn redox ruthenium spectroelectrochem tetraiminobiphenyl]

F. Albert Cotton, William H. Ilsley, and Wolfgang. Kaim. Chelate rings in a quadruply bonded dimetal compound: Preparation and structure of diacetatodi(4-phenylimino-2-pentanonato)dimolybdenum. Inorganica Chimica Acta, (37)2:267--272, 1979. [PUMA: acetato binuclear complex;structure molybdenum phenyliminopentanonato]

Wolfgang Kaim, and Stephan. Kohlmann. Semireduced bridging ligands containing N-N multiple bond coordination sites. ESR study of binuclear Group 6 metal carbonyl complexes. Inorganic Chemistry, (25)19:3442--3448, 1986. [PUMA: ESR ESR;ENDOR ESR;tetrazine VIB azobipyridine azopyridine binuclear carbonyl complex complex;ESR complex;pyridyltetrazine molybdenum]

Liladhar B. Kumbhare, Amey P. Wadawale, Vimal K. Jain, Monika Sieger, and Wolfgang. Kaim. Binuclear rhodium(III) and iridium(III) monoselenocarboxylates: Synthesis, spectroscopy and structure of an ortho-metalated iridium complex featuring an IrCCC(m-Se) chelate ring. Inorganic Chemistry Communications, (13)4:475--478, 2010. [PUMA: binuclear bridged complex complex;rhodium crystal iridium metalated monoselenocarboxylate ortho phenylcarboselenolate prepn prepn;mol structure]

Sascha Berger, Thomas Scheiring, Jan Fiedler, and Wolfgang. Kaim. Coupling of organometallic reaction centers through the non-planar bridging ligand 2,3-bis(2-pyridyl)pyrazine. Zeitschrift fuer Anorganische und Allgemeine Chemie, (630)13-14:2409--2417, 2004. [PUMA: binuclear bis complex complex;mol complex;redox complex;rhodium crystal half iridium mononuclear pentamethylcyclopentadienyl potential prepn pyridylpyrazine rhodium sandwich structure]

Wolfgang. Kaim. Coordination chemistry of reduced nitrogen heterocycles. Dinuclear pentacarbonyl complexes of molybdenum and tungsten with paramagnetic bridging ligands. Chemische Berichte, (115)3:910--918, 1982. [PUMA: binuclear carbonyl complex nitrogen tungsten bipyridine complex;carbonyl complex;molybdenum complex;pyrazine complex;quinoxaline complex;tungsten heterocycle heterocycle;dipyridylethene heterocycle;phenazine molybdenum]

F. Albert Cotton, William H. Ilsley, and Wolfgang. Kaim. Homologous chromium, molybdenum, and tungsten derivatives of 6-chloro-2-hydroxypyridine. Inductive effects on the metal-metal bond length. Inorganic Chemistry, (19)6:1453--1457, 1980. [PUMA: binuclear binuclear;tungsten bond bond;inductive bond;molybdenum bond;structure chlorohydroxypyridine chromium effect metal transition]

Paul S. Braterman, Jae Inh Song, Stephan Kohlmann, Conny Vogler, and Wolfgang. Kaim. Spectroelectrochemistry of aromatic ligands and their derivatives. III. Binuclear transition metal complexes of copper(I), molybdenum(0), and rhenium(I) with 2,2'-bipyrimidine. Journal of Organometallic Chemistry, (411)1-2:207--213, 1991. [PUMA: binuclear bipyrimidine carbonyl complex copper electronic electroredn;transition metal potential redn rhenium spectrum spectrum;molybdenum visible]

Frank Baumann, Wolfgang Kaim, Gert Denninger, Hans-Juergen Kuemmerer, and Jan. Fiedler. Widely Separated Reduction Processes of abpy-Coupled Areneosmium(II) Reaction Centers (abpy = 2,2'-Azobispyridine): Stabilization of the Radical Intermediate and of the Os0OsII State. Organometallics, (24)8:1966--1973, 2005. [PUMA: EPR arene azobispyridine binuclear bipyrimidine bridged cation complex complex;osmium diosmium mixed osmium potential;radical redox spectra valence]

Wolfgang Kaim, Sascha Berger, Stefan Greulich, Ralf Reinhardt, and Jan. Fiedler. Electronic coupling of two Cp*ClM+/Cp*M reaction centers via p conjugated bridging ligands: Similarities and differences between rhodium and iridium analogues. Journal of Organometallic Chemistry, (582)2:153--159, 1999. [PUMA: bidentate binuclear bispyridinyltetrazine center;iridium complex coupling diiridium dirhodium electron intermediate iridium redn redox rhodium spectroelectrochem;mixed tetrazinebispyrinyl valent]

F. Albert Cotton, William H. Ilsley, and Wolfgang. Kaim. A mixed-ligand complex of quadruply bonded ditungsten(II): Bis(2,4-dimethyl-6-oxopyrimidine)bis(1,3-diphenyltriazeno)ditungsten. Inorganic Chemistry, (19)6:1450--1452, 1980. [PUMA: binuclear binuclear;structure diphenyl diphenyltriazene diphenyltriazene;triazene oxo oxopyrimidine pyrimidine tungsten]

F. Albert Cotton, William H. Ilsley, and Wolfgang. Kaim. Some reactions of the octahalodirhenate(III) ions. 11. Two new quadrupoly bonded dirhenium amidinato-bridged complexes. Inorganic Chemistry, (19)8:2360--2364, 1980. [PUMA: amidinato binuclear complex rhenium structure]

Michael Subat, Kristina Woinaroschy, Corinna Gerstl, Biprajit Sarkar, Wolfgang Kaim, and Burkhard. Koenig. 1,4,7,10-Tetraazacyclododecane metal complexes as potent promoters of phosphodiester hydrolysis under physiological conditions. Inorganic Chemistry, (47)11:4661--4668, 2008. [PUMA: binuclear bipyridinyl bridged catalyst catalyst;zinc hydrolysis kinetics mononuclear nitrophenyl phosphate pyridinyl tetraazacyclododecane triazine triazinyl zinc]