Lithium (4-phenylimino)-2-pentanonate reacts with Mo2(O2CMe)4 to replace 2 acetate ligands and afford red, cryst. Mo2(O2CMe)2PhNCMeCHCMe(O)2. The crystal and mol. structures were detd. by x-ray crystallog. The crystals belong to space group P1̅ with a 11.723(3), b 10.402(2), c 12.624(2) \AA; a 112.88(1)°, b 95.04(1)°, g 107.01(1)°, and Z = 2. The structure has cisoid arrangement of the bridging acetate ligands and 1 chelate ring on each metal atom. The unsym. chelate ligands are so arranged that the virtual symmetry is C2. The Mo-Mo distance is 2.131(1) \AA. on SciFinder(R)
%0 Journal Article
%1 Cotton.1979b
%A Cotton, F. Albert
%A Ilsley, William H.
%A Kaim, Wolfgang.
%D 1979
%J Inorganica Chimica Acta
%K acetato binuclear complex;structure molybdenum phenyliminopentanonato
%N 2
%P 267--272
%R 10.1016/S0020-1693(00)95556-7
%T Chelate rings in a quadruply bonded dimetal compound: Preparation and structure of diacetatodi(4-phenylimino-2-pentanonato)dimolybdenum
%V 37
%X Lithium (4-phenylimino)-2-pentanonate reacts with Mo2(O2CMe)4 to replace 2 acetate ligands and afford red, cryst. Mo2(O2CMe)2PhNCMeCHCMe(O)2. The crystal and mol. structures were detd. by x-ray crystallog. The crystals belong to space group P1̅ with a 11.723(3), b 10.402(2), c 12.624(2) \AA; a 112.88(1)°, b 95.04(1)°, g 107.01(1)°, and Z = 2. The structure has cisoid arrangement of the bridging acetate ligands and 1 chelate ring on each metal atom. The unsym. chelate ligands are so arranged that the virtual symmetry is C2. The Mo-Mo distance is 2.131(1) \AA. on SciFinder(R)
@article{Cotton.1979b,
abstract = {Lithium (4-phenylimino)-2-pentanonate reacts with Mo2(O2CMe)4 to replace 2 acetate ligands and afford red, cryst. Mo2(O2CMe)2[PhNCMeCHCMe(O)]2. The crystal and mol. structures were detd. by x-ray crystallog. The crystals belong to space group P1̅ with a 11.723(3), b 10.402(2), c 12.624(2) {\AA}; \textgreek{a} 112.88(1)°, \textgreek{b} 95.04(1)°, \textgreek{g} 107.01(1)°, and Z = 2. The structure has cisoid arrangement of the bridging acetate ligands and 1 chelate ring on each metal atom. The unsym. chelate ligands are so arranged that the virtual symmetry is C2. The Mo-Mo distance is 2.131(1) {\AA}. [on SciFinder(R)]},
added-at = {2019-07-15T13:41:23.000+0200},
author = {Cotton, F. Albert and Ilsley, William H. and Kaim, Wolfgang.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2328692a47d62584c32a9624937118f92/b_schwederski},
doi = {10.1016/S0020-1693(00)95556-7},
interhash = {33c2394bb66936156641efb321bf9db6},
intrahash = {328692a47d62584c32a9624937118f92},
issn = {0020-1693},
journal = {Inorganica Chimica Acta},
keywords = {acetato binuclear complex;structure molybdenum phenyliminopentanonato},
number = 2,
pages = {267--272},
timestamp = {2019-07-15T11:42:10.000+0200},
title = {Chelate rings in a quadruply bonded dimetal compound: Preparation and structure of diacetatodi(4-phenylimino-2-pentanonato)dimolybdenum},
volume = 37,
year = 1979
}
