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Coordination chemistry of reduced nitrogen heterocycles. Dinuclear pentacarbonyl complexes of molybdenum and tungsten with paramagnetic bridging ligands

. Chemische Berichte 115 (3): 910--918 (1982)

Zusammenfassung

LM(CO)52- (M = Mo, W; L = pyrazine, 2,5-dimethylpyrazine, quinoxaline, phenazine, 4,4'-bipyridine, (E)-1,2-di-4-pyridylethene) were prepd. by reaction of M(CO)6 with the radical anions of the heterocycles L in THF or dimethoxyethane. The metal carbonyl coordination was established by high resoln. ESR which also provided data on the spin distribution and on the conformation of the radical complexes. on SciFinder(R)

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BibTeX-Schlüssel:
Kaim.1982e
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