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2,5-Dioxido-1,4-benzoquinonediimine (H2L2-), a hydrogen-bonding noninnocent bridging ligand related to aminated topaquinone: Different oxidation state distributions in complexes [(bpy)2Ru2(m-H2L)]n (n = 0 , +, 2+, 3+, 4+) and [(acac)2Ru2(m-H2L)]m (m = 2-, -, 0, +, 2+)

S. Kar, B. Sarkar, S. Ghumaan, D. Janardanan, J. van Slageren, J. Fiedler, V. Puranik, R. Sunoj, W. Kaim, and G. Lahiri. Chemistry - A European Journal, 11 (17): 4901--4911 (2005)
DOI: 10.1002/chem.200500202

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Dr. Pranav Kumar University of Stuttgart

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Manish Kumar University of Stuttgart

Tarun Kumar Mitruka Vinod Kumar Mitruka University of Stuttgart

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Reductive Approach to Mixed Valency (n = 1-) in the Pyrazine Ligand-Bridged [(acac)2Ru(m-L2-)Ru(acac)2]n (L2- = 2,5-Pyrazine-dicarboxylate) through Experiment and TheoryA. Das, T. Scherer, S. Maji, T. Mondal, S. Mobin, F. Urbanos, R. Jimenez-Aparicio, W. Kaim, and G. Lahiri. Inorganic Chemistry, 50 (15): 7040--7049 (2011)A New Coordination Mode of the Photometric Reagent Glyoxalbis(2-hydroxyanil) (H2gbha): Bis-Bidentate Bridging by gbha2- in the Redox Series (μ-gbha)[Ru(acac)2]2n (n = -2, -1, 0, +1, +2), Including a Radical-Bridged Diruthenium(III) and a RuIII/RuIV IntermediateS. Kar, B. Sarkar, S. Ghumaan, D. Roy, F. Urbanos, J. Fiedler, R. Sunoj, R. Jimenez-Aparicio, W. Kaim, and G. Lahiri. Inorganic Chemistry, 44 (24): 8715--8722 (2005)Uncommon cis Configuration of a Metal-Metal Bridging Noninnocent Nindigo LigandP. Mondal, S. Plebst, R. Ray, S. Mobin, W. Kaim, and G. Lahiri. Inorganic Chemistry, 53 (17): 9348--9356 (2014)Isovalent and Mixed-Valent Diruthenium Complexes [(acac)2RuII(m-bpytz)RuII(acac)2] and [(acac)2RuII(m-bpytz)RuIII(acac)2](ClO4) (acac = Acetylacetonate and bpytz = 3,6-Bis(3,5-dimethylpyrazolyl)-1,2,4,5-tetrazine): Synthesis, Spectroelectrochemical, and EPR InvestigationS. Patra, B. Sarkar, S. Ghumaan, J. Fiedler, W. Kaim, and G. Lahiri. Inorganic Chemistry, 43 (19): 6108--6113 (2004)Unconventional mixed-valent complexes of ruthenium and osmiumW. Kaim, and G. Lahiri. Angewandte Chemie, International Edition, 46 (11): 1778--1796 (2007)The intricate paramagnetic state of [Os(Q)2(bpy)]+, Q = 4,6-di-tert-butyl-o-iminobenzoquinoneD. Das, T. Scherer, A. Das, T. Mondal, S. Mobin, J. Fiedler, J. Priego, R. Jimenez-Aparicio, W. Kaim, and G. Lahiri. Dalton Transactions, 41 (38): 11675--11683 (2012)Strong metal-metal coupling in mixed-valent intermediates [Cl(L)Ru(m-tppz)Ru(L)Cl]+, L = b-diketonato ligands, tppz = 2,3,5,6-tetrakis(2-pyridyl)pyrazineT. Kundu, D. Schweinfurth, B. Sarkar, T. Mondal, J. Fiedler, S. Mobin, V. Puranik, W. Kaim, and G. Lahiri. Dalton Transactions, 41 (43): 13429--13440 (2012)Valence structures of the diastereomeric complexes meso- and rac-[Ru2(acac)4(m-Q)]n (n = 2-, 1-, 0, 1+, 2+) with the multiple quinonoid bridging ligand Q = 1,2,4,5-tetraimino-3,6-diketocyclohexaneD. Kumbhakar, B. Sarkar, A. Das, A. Das, S. Mobin, J. Fiedler, W. Kaim, and G. Lahiri. Dalton Transactions, (2009)Correspondence of Ru(III) Ru(II) and Ru(IV) Ru(III) mixed valent states in a small dinuclear complexH. Agarwala, T. Scherer, S. Maji, T. Mondal, S. Mobin, J. Fiedler, F. Urbanos, R. Jimenez-Aparicio, W. Kaim, and G. Lahiri. Chemistry (Weinheim an der Bergstrasse, Germany), 18 (18): 5667--5675 (2012)Controlling metal-ligand-metal oxidation state combinations by ancillary ligand (L) variation in the redox systems [L2Ru(mu-boptz)RuL2]n, boptz = 3,6-bis(2-oxidophenyl)-1,2,4,5-tetrazine, and L = acetylacetonate, 2,2'-bipyridine, or 2-phenylazopyridineS. Patra, B. Sarkar, S. Maji, J. Fiedler, F. Urbanos, R. Jimenez-Aparicio, W. Kaim, and G. Lahiri. Chemistry - A European Journal, 12 (2): 489--498 (2005)