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Reductive Approach to Mixed Valency (n = 1-) in the Pyrazine Ligand-Bridged (acac)2Ru(m-L2-)Ru(acac)2n (L2- = 2,5-Pyrazine-dicarboxylate) through Experiment and Theory

A. Das, T. Scherer, S. Maji, T. Mondal, S. Mobin, F. Urbanos, R. Jimenez-Aparicio, W. Kaim, and G. Lahiri. Inorganic Chemistry, 50 (15): 7040--7049 (2011)
DOI: 10.1021/ic200530u

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Somnath Bhattacharya University of Stuttgart

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Formation, reactivity, and photorelease of metal bound nitrosyl in Ru(trpy)(L)(NO)n+ (trpy = 2,2':6',2''-terpyridine, L = 2-phenylimidazo4,5-f1,10-phenanthroline)S. Maji, B. Sarkar, M. Patra, A. Das, S. Mobin, W. Kaim, and G. Lahiri. Inorganic Chemistry, 47 (8): 3218--3227 (2008)Intramolecular Valence and Spin Interaction in meso and rac Diastereomers of a p-Quinonoid-Bridged Diruthenium ComplexD. Kumbhakar, B. Sarkar, S. Maji, S. Mobin, J. Fiedler, F. Urbanos, R. Jimenez-Aparicio, W. Kaim, and G. Lahiri. Journal of the American Chemical Society, 130 (51): 17575--17583 (2008)Valence-state analysis through spectroelectrochemistry in a series of quinonoid-bridged diruthenium complexes (acac)2Ru(m-L)Ru(acac)2n (n = +2, +1, 0, -1, -2)S. Ghumaan, B. Sarkar, S. Maji, V. Puranik, J. Fiedler, F. Urbanos, R. Jimenez-Aparicio, W. Kaim, and G. Lahiri. Chemistry - A European Journal, 14 (34): 10816--10828 (2008)Controlling metal-ligand-metal oxidation state combinations by ancillary ligand (L) variation in the redox systems L2Ru(m-boptz)RuL2n, boptz = 3,6-bis(2-hydroxyphenyl)-1,2,4,5-tetrazine(2-), and L = acetylacetonate, 2,2'-bipyridine, or 2-phenylazopyridineS. Patra, B. Sarkar, S. Maji, J. Fiedler, F. Urbanos, R. Jimenez-Aparicio, W. Kaim, and G. Lahiri. Chemistry - A European Journal, 12 (2): 489--498 (2006)Electronic structure and catalytic aspects of Ru(tpm)(bqdi)(Cl/H2O)n, tpm = tris(1-pyrazolyl)methane and bqdi = o-benzoquinonediimineH. Agarwala, F. Ehret, A. Chowdhury, S. Maji, S. Mobin, W. Kaim, and G. Lahiri. Dalton Transactions, 42 (10): 3721--3734 (2013)Correspondence of Ru(III) Ru(II) and Ru(IV) Ru(III) mixed valent states in a small dinuclear complexH. Agarwala, T. Scherer, S. Maji, T. Mondal, S. Mobin, J. Fiedler, F. Urbanos, R. Jimenez-Aparicio, W. Kaim, and G. Lahiri. Chemistry (Weinheim an der Bergstrasse, Germany), 18 (18): 5667--5675 (2012)Controlling metal-ligand-metal oxidation state combinations by ancillary ligand (L) variation in the redox systems L2Ru(mu-boptz)RuL2n, boptz = 3,6-bis(2-oxidophenyl)-1,2,4,5-tetrazine, and L = acetylacetonate, 2,2'-bipyridine, or 2-phenylazopyridineS. Patra, B. Sarkar, S. Maji, J. Fiedler, F. Urbanos, R. Jimenez-Aparicio, W. Kaim, and G. Lahiri. Chemistry - A European Journal, 12 (2): 489--498 (2005)Reductive Approach to Mixed Valency (n = 1-) in the Pyrazine Ligand-Bridged (acac)2Ru(m-L2-)Ru(acac)2n (L2- = 2,5-Pyrazine-dicarboxylate) through Experiment and TheoryA. Das, T. Scherer, S. Maji, T. Mondal, S. Mobin, F. Urbanos, R. Jimenez-Aparicio, W. Kaim, and G. Lahiri. Inorganic Chemistry, 50 (15): 7040--7049 (2011)Metal-Induced Reductive Ring Opening of 1,2,4,5-Tetrazines: Three Resulting Coordination Alternatives, Including the New Non-Innocent 1,2-Diiminohydrazido(2-) Bridging Ligand SystemS. Maji, B. Sarkar, S. Patra, J. Fiedler, S. Mobin, V. Puranik, W. Kaim, and G. Lahiri. Inorganic Chemistry, 45 (3): 1316--1325 (2006)Stabilization of RuNO6 and RuNO7 States in RuII(trpy)(bik)(NO)n+ trpy = 2,2':6',2''-terpyridine, bik = 2,2'-bis(1-methylimidazolyl) ketone - Formation, Reactivity, and Photorelease of Metal-Bound NitrosylP. De, B. Sarkar, S. Maji, A. Das, E. Bulak, S. Mobin, W. Kaim, and G. Lahiri. European Journal of Inorganic Chemistry, (2009)