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Electron transfer induced metal addition and ligand exchange in organometallic anion radical complexes

W. Kaim, B. Olbrich-Deussner, R. Gross, S. Ernst, S. Kohlmann, and C. Bessenbacher. NATO ASI Series, Series C: Mathematical and Physical Sciences, 257 (Paramagn. Organomet. Species Act./Sel., Catal): 283--294 (1989)

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Christoph Olbrich University of Stuttgart

Barbara Krämer University of Stuttgart

Dr. Barbara Reisinger University of Stuttgart

Apl. Prof. Dr. Barbara Potthast University of Stuttgart

Barbara Reyer University of Stuttgart

Other publications of authors with the same name

What determines the solvatochromism of metal-to-ligand charge transfer transitions? A demonstration involving 17 tungsten carbonyl complexesW. Kaim, S. Kohlmann, S. Ernst, B. Olbrich-Deussner, C. Bessenbacher, and A. Schulz. Journal of Organometallic Chemistry, 321 (2): 215--226 (1987)Specific solvatochromism of the prototypical olefin complexes (h2-TCNE)M(CO)5 (M = chromium, tungsten) resulting from n and p donation of aprotic solvents toward the p-acceptor ligandW. Kaim, B. Olbrich-Deussner, and T. Roth. Organometallics, 10 (2): 410--415 (1991)Resonance Raman study of (h2-TCNE)M(CO)5 (M = Cr, W; TCNE = tetracyanoethene). Evidence for an olefin-complex $\rightarrow$ metallacyclopropane transition upon low-energy metal-to-ligand charge-transfer excitationD. Stufkens, T. Snoeck, W. Kaim, T. Roth, and B. Olbrich-Deussner. Journal of Organometallic Chemistry, 409 (1-2): 189--195 (1991)Electron transfer induced metal addition and ligand exchange in organometallic anion radical complexesW. Kaim, B. Olbrich-Deussner, R. Gross, S. Ernst, S. Kohlmann, and C. Bessenbacher. NATO ASI Series, Series C: Mathematical and Physical Sciences, 257 (Paramagn. Organomet. Species Act./Sel., Catal): 283--294 (1989)Electron transfer catalyzed substitution in carbonyl complexes. IV. Mononuclear s- and p-coordinated complexes of manganese, chromium and tungsten with tetracyanoethylene and tetracyano-p-quinodimethaneB. Olbrich-Deussner, R. Gross, and W. Kaim. Journal of Organometallic Chemistry, 366 (1-2): 155--174 (1989)Paramagnetic main Group and transition metal complexes containing unsaturated nitrogen ligandsW. Kaim, and B. Olbrich-Deussner. Journal of Organometallic Chemistry Library, 22 (Organomet. Radical Processes): 173--200 (1990)Unexpected paramagnetism of mono- and polynuclear 18 valence electron metal carbonyl complexes [(CnRn)(CO)2M]k(L), M = chromium, manganese; k = 1, 2, 4. Implications for photoreactivityW. Kaim, T. Roth, B. Olbrich-Deussner, R. Gross-Lannert, J. Jordanov, and E. Roth. Journal of the American Chemical Society, 114 (14): 5693--5697 (1992)Electron transfer catalyzed substitution in carbonyl complexes VI. Highly variable rates of substitution by tetracyanoethyleneB. Schwederski, W. Kaim, B. Olbrich-Deussner, and T. Roth. Journal of Organometallic Chemistry, 440 (1-2): 145--152 (1992)Electron transfer catalyzed carbonyl substitution. I. Synthesis and spectroscopy of phosphine tricarbonyl metal complexes of bidiazineB. Olbrich-Deussner, and W. Kaim. Journal of Organometallic Chemistry, 340 (1): 71--91 (1988)Electron delocalization in molecule-bridged polymetallic systems. Unique neutral complexes of TCNE or TCNQ and up to four organometallic fragments (C5R5)(CO)2MnR. Gross-Lannert, W. Kaim, and B. Olbrich-Deussner. Inorganic Chemistry, 29 (25): 5046--5053 (1990)