%0 Journal Article %1 Kaim.1989c %A Kaim, Wolfgang %A Olbrich-Deussner, Barbara %A Gross, Renate %A Ernst, Sylvia %A Kohlmann, Stephan %A Bessenbacher, Christian. %D 1989 %J NATO ASI Series, Series C: Mathematical and Physical Sciences %K anion complex electron formation metal reaction review;polynuclear review;review transfer transition %N Paramagn. Organomet. Species Act./Sel., Catal %P 283--294 %T Electron transfer induced metal addition and ligand exchange in organometallic anion radical complexes %V 257 %X A review with $\sim$60 refs. Transition metal complexes contg. anion radical ligands display a strong tendency towards full coordinative satn. at the singly reduced ligand and towards substitutional activation of co-ligands at the metal center. Examples involving metal carbonyls show how both of these reactivities can be employed either sep. or in a combined fashion for electron transfer catalyzed substitution processes and for the construction of new polynuclear complexes with unusual properties. [on SciFinder(R)]

@article{Kaim.1989c, abstract = {A review with $\sim$60 refs. Transition metal complexes contg. anion radical ligands display a strong tendency towards full coordinative satn. at the singly reduced ligand and towards substitutional activation of co-ligands at the metal center. Examples involving metal carbonyls show how both of these reactivities can be employed either sep. or in a combined fashion for electron transfer catalyzed substitution processes and for the construction of new polynuclear complexes with unusual properties. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Kaim, Wolfgang and Olbrich-Deussner, Barbara and Gross, Renate and Ernst, Sylvia and Kohlmann, Stephan and Bessenbacher, Christian.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2d9b2eacfb70d51cf19987cbb9aa7f194/huebleriac}, interhash = {af06063666b48fcbd9e5e63f1129de8a}, intrahash = {d9b2eacfb70d51cf19987cbb9aa7f194}, issn = {0258-2023}, journal = {NATO ASI Series, Series C: Mathematical and Physical Sciences}, keywords = {anion complex electron formation metal reaction review;polynuclear review;review transfer transition}, number = {Paramagn. Organomet. Species Act./Sel., Catal}, pages = {283--294}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Electron transfer induced metal addition and ligand exchange in organometallic anion radical complexes}, volume = 257, year = 1989 }