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Structure, EPR and UV-VIS and IR spectroelectrochemistry of reversibly reducible compounds [(C5Me5)IrCl(L)](PF6), L= 1,3-dimethyllumazine or 1,3-dimethylalloxazine

O. Heilmann, F. Hornung, W. Kaim, and J. Fiedler. Journal of the Chemical Society, Faraday Transactions, 92 (21): 4233--4238 (1996)
DOI: 10.1039/FT9969204233

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Tim Hornung University of Stuttgart

Florian Hornung University of Stuttgart

Cordula Hornung University of Stuttgart

Hon. -Prof. Dr. -Ing. Dr. Roland Hornung University of Stuttgart

M. Fittingho

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New sulfide-bridged heterocubanes [MVI(S)ReI3(CO)9(m3-S)4]-, M = Mo or W, with transition metals in very different oxidation statesF. Hornung, K. Klinkhammer, and W. Kaim. Chemical Communications (Cambridge, United Kingdom), (1998)Spectroelectrochemical Characterization of the Two-Step Redox System (μ-pz)[Os(CN)5]2n- (n = 4, 5, 6; pz = Pyrazine). Similarities and Differences in Relation to the Creutz-Taube System. [Erratum to document cited in CA128:56656]F. Hornung, F. Baumann, W. Kaim, J. Olabe, L. Slep, and J. Fiedler. Inorganic Chemistry, 37 (20): 5402 (1998)Metal vs. Ligand Reduction in Complexes of 1,3-Dimethylalloxazine (DMA) with Copper(I), Ruthenium(II), and Tungsten(VI). Crystal Structures of (DMA)WO2Cl2 and (Bis(1-methylimidazol-2-yl)ketone)WO2Cl2F. Hornung, O. Heilmann, W. Kaim, S. Zalis, and J. Fiedler. Inorganic Chemistry, 39 (18): 4052--4058 (2000)Spectroelectrochemical Characterization of the Two-Step Redox System (μ-pz)[Os(CN)5]2n- (n = 4, 5, 6; pz = Pyrazine). Similarities and Differences in Relation to the Creutz-Taube SystemF. Hornung, F. Baumann, W. Kaim, J. Olabe, L. Slep, and J. Fiedler. Inorganic Chemistry, 37 (2): 311--316 (1998)Di- and trinuclear complexes of WS42- with tricarbonylrhenium(I) and -manganese(I) fragments. Structure, spectroscopy, and electrochemistryW. Kaim, F. Hornung, R. Schaefer, B. Schwederski, and J. Fiedler. Zeitschrift fuer Anorganische und Allgemeine Chemie, 624 (7): 1211--1220 (1998)Electronic and molecular structure of 2,2'-bipyrimidine-bridged bis(organoplatinum) complexes in various oxidation states. Radical-bridged diplatinum species and the absence of a Pt(III)/Pt(II) mixed-valent intermediateA. Klein, W. Kaim, F. Hornung, J. Fiedler, and S. Zalis. Inorganica Chimica Acta, 264 (1-2): 269--278 (1997)Organometallic iridium(III) and rhenium(I) complexes with lumazine, alloxazine and pterin derivativesO. Heilmann, F. Hornung, J. Fiedler, and W. Kaim. Journal of Organometallic Chemistry, 589 (1): 2--10 (1999)Structure, EPR and UV-VIS and IR spectroelectrochemistry of reversibly reducible compounds [(C5Me5)IrCl(L)](PF6), L= 1,3-dimethyllumazine or 1,3-dimethylalloxazineO. Heilmann, F. Hornung, W. Kaim, and J. Fiedler. Journal of the Chemical Society, Faraday Transactions, 92 (21): 4233--4238 (1996)Sensitive valence tautomer equilibrium of paramagnetic complexes [(L)Cun+(Qn-)] (n = 1 or 2; Q = quinones) related to amine oxidase enzymesJ. Rall, M. Wanner, M. Albrecht, F. Hornung, and W. Kaim. Chemistry - A European Journal, 5 (10): 2802--2809 (1999)