%0 Journal Article %1 Hornung.1998c %A Hornung, Fridmann M. %A Klinkhammer, Karl Wilhelm %A Kaim, Wolfgang. %D 1998 %J Chemical Communications (Cambridge, United Kingdom) %K carbonyl charge heterocubane heterocubane;crystal heterocubane;cubane heterocubane;rhenium heterocubane;tungsten molybdenum potential prepn prepn;molybdenum prepn;redn prepn;structure rhenium structure sulfido sulfidorhenium transfer tungsten %N 18 %P 2055--2056 %R 10.1039/a805295f %T New sulfide-bridged heterocubanes MVI(S)ReI3(CO)9(m3-S)4-, M = Mo or W, with transition metals in very different oxidation states %X (NEt4)MVI(S)ReI3(CO)9(m3-S)4 (M = Mo, W) were prepd. and found to contain 3 6-coordinate tricarbonylrhenium(I) fragments, held together by 1 m3-sulfide ion and by 1 reducible and charge transfer-active m3-MVIS42- unit. Crystal data are reported in space group P21/n for the isomorphic complex salts. UV-visible spectra including metal-metal charge transfer is discussed. on SciFinder(R)

@article{Hornung.1998c, abstract = {(NEt4)[MVI(S)ReI3(CO)9(\textgreek{m}3-S)4] (M = Mo, W) were prepd. and found to contain 3 6-coordinate tricarbonylrhenium(I) fragments, held together by 1 \textgreek{m}3-sulfide ion and by 1 reducible and charge transfer-active \textgreek{m}3-MVIS42- unit. Crystal data are reported in space group P21/n for the isomorphic complex salts. UV-visible spectra including metal-metal charge transfer is discussed. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Hornung, Fridmann M. and Klinkhammer, Karl Wilhelm and Kaim, Wolfgang.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2cbce07fe3fce97a8956a94b4877c6e5d/huebleriac}, doi = {10.1039/a805295f}, interhash = {fe6b47fb6bdc73e3530d248e0f8279b8}, intrahash = {cbce07fe3fce97a8956a94b4877c6e5d}, issn = {1359-7345}, journal = {Chemical Communications (Cambridge, United Kingdom)}, keywords = {carbonyl charge heterocubane heterocubane;crystal heterocubane;cubane heterocubane;rhenium heterocubane;tungsten molybdenum potential prepn prepn;molybdenum prepn;redn prepn;structure rhenium structure sulfido sulfidorhenium transfer tungsten}, number = 18, pages = {2055--2056}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {New sulfide-bridged heterocubanes [MVI(S)ReI3(CO)9(\textgreek{m}3-S)4]-, M = Mo or W, with transition metals in very different oxidation states}, year = 1998 }