%0 Journal Article %1 Bessenbacher.1985 %A Bessenbacher, Christian %A Gross, Renate %A Kaim, Wolfgang. %D 1985 %J Journal of the Chemical Society, Chemical Communications %K acetylpyrazine bisdimethylphosphinothioylpyrazine cation;methylphosphinothioylpyrazine diacetyl diacetylpyrazine dimethylphosphinothioyl electrochem oxidn oxidn;ESR oxidn;pyrazine radical %N 20 %P 1369--1370 %R 10.1039/c39850001369 %T Persistent cation radicals containing carboxamide and thiophosphinic amide functions. The one electron oxidation of acceptor stabilized 1,4-dihydropyrazines %X An electrochem. study showed that the 1,4-dihydropyrazine system (I; R = H) is sufficiently p electron rich to accommodate the p accepting N-substituents in I [R = Ac, P(S)Me2], without losing its propensity to undergo one electron oxidn. to give the corresponding persistent radical cations. These radicals were characterized by ESR spectroscopy. [on SciFinder(R)]

@article{Bessenbacher.1985, abstract = {An electrochem. study showed that the 1,4-dihydropyrazine system (I; R = H) is sufficiently \textgreek{p} electron rich to accommodate the \textgreek{p} accepting N-substituents in I [R = Ac, P(S)Me2], without losing its propensity to undergo one electron oxidn. to give the corresponding persistent radical cations. These radicals were characterized by ESR spectroscopy. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Bessenbacher, Christian and Gross, Renate and Kaim, Wolfgang.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/21a7c41b9ea24e986cdb51df56c58efcd/huebleriac}, doi = {10.1039/c39850001369}, interhash = {e0944f2d0935d93e18a4894684359953}, intrahash = {1a7c41b9ea24e986cdb51df56c58efcd}, issn = {0022-4936}, journal = {Journal of the Chemical Society, Chemical Communications}, keywords = {acetylpyrazine bisdimethylphosphinothioylpyrazine cation;methylphosphinothioylpyrazine diacetyl diacetylpyrazine dimethylphosphinothioyl electrochem oxidn oxidn;ESR oxidn;pyrazine radical}, number = 20, pages = {1369--1370}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Persistent cation radicals containing carboxamide and thiophosphinic amide functions. The one electron oxidation of acceptor stabilized 1,4-dihydropyrazines}, year = 1985 }