%0 Journal Article %1 Hoshino.2003 %A Hoshino, Yoshimasa %A Higuchi, Seiichiro %A Fiedler, Jan %A Su, Cheng-Yong %A Knodler, Axel %A Schwederski, Brigitte %A Sarkar, Biprajit %A Hartmann, Heiko %A Kaim, Wolfgang. %D 2003 %J Angewandte Chemie, International Edition %K complex diketone dinuclear electrochem ethynylated redox ruthenium %N 6 %P 674--677 %R 10.1002/anie.200390186 %T Long-range electronic coupling in various oxidation states of a C4-linked tris(b-diketonato)ruthenium dimer %V 42 %X Long metal-metal sepn. may affect the Coulomb-detd. Kc value as derived from the difference in electrochem. potential whereas the electronic interaction is more influenced by the correlation between the configurations of the metal centers and the properties of the bridging ligand in diacetylene bridged dinuclear ruthenium b-diketone complexes. Electrochem. redox studies show that the spacers can be combined with robust Werner-type coordination complexes to achieve variable, potentially very strong electronic coupling across large distances. on SciFinder(R)

@article{Hoshino.2003, abstract = {Long metal-metal sepn. may affect the Coulomb-detd. Kc value as derived from the difference in electrochem. potential whereas the electronic interaction is more influenced by the correlation between the configurations of the metal centers and the properties of the bridging ligand in diacetylene bridged dinuclear ruthenium \textgreek{b}-diketone complexes. Electrochem. redox studies show that the spacers can be combined with robust Werner-type coordination complexes to achieve variable, potentially very strong electronic coupling across large distances. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Hoshino, Yoshimasa and Higuchi, Seiichiro and Fiedler, Jan and Su, Cheng-Yong and Knodler, Axel and Schwederski, Brigitte and Sarkar, Biprajit and Hartmann, Heiko and Kaim, Wolfgang.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/24316b2b05284ba67f7e5b9667b1ac7b7/huebleriac}, doi = {10.1002/anie.200390186}, interhash = {cd2272c88b3f2ef5ab3acca43ba14811}, intrahash = {4316b2b05284ba67f7e5b9667b1ac7b7}, issn = {1433-7851}, journal = {Angewandte Chemie, International Edition}, keywords = {complex diketone dinuclear electrochem ethynylated redox ruthenium}, number = 6, pages = {674--677}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Long-range electronic coupling in various oxidation states of a C4-linked tris(\textgreek{b}-diketonato)ruthenium dimer}, volume = 42, year = 2003 }