%0 Journal Article %1 Sinhababu.2019 %A Sinhababu, Soumen %A Kundu, Subrata %A Siddiqui, Mujahuddin M. %A Paesch, Alexander N. %A Herbst-Irmer, Regine %A Schwederski, Brigitte %A Saha, Pinaki %A Zhao, Lili %A Frenking, Gernot %A Kaim, Wolfgang %A Stalke, Dietmar %A Roesky, Herbert W. %D 2019 %J Chemical Communications (Cambridge, United Kingdom) %K alkylaminocarbene biradical cAAC complex complex;EPR complex;mol complex;silylene crystal cyclic prepn radical silylene spectra stabilized structure %N 31 %P 4534--4537 %R 10.1039/c9cc01448a %T Synthesis of cAAC stabilized biradical of \textquotedblMe2Si\textquotedbl and \textquotedblMe2SiCl\textquotedbl monoradical from Me2SiCl2 - an important feedstock material %V 55 %X The cyclic alkyl(amino) carbene (cAAC) coordinated biradical of dimethylsilicon was isolated as (cAAC)2Me2Si (1, cAAC = 1-Dipp-2,2,4,4-tetramethyl-2-pyrrolidinylidene), synthesized from the redn. of Me2SiCl2 using two equiv. of KC8 in the presence of two equiv of cAAC. The redn. of Me2SiCl2 by one equiv of KC8 in the presence of one equiv of cAAC resulted in the stable dimethylsiliconchloride monoradical (cAAC)Me2SiCl (2). [on SciFinder(R)]

@article{Sinhababu.2019, abstract = {The cyclic alkyl(amino) carbene (cAAC) coordinated biradical of dimethylsilicon was isolated as (cAAC)2Me2Si (1, cAAC = 1-Dipp-2,2,4,4-tetramethyl-2-pyrrolidinylidene), synthesized from the redn. of Me2SiCl2 using two equiv. of KC8 in the presence of two equiv of cAAC. The redn. of Me2SiCl2 by one equiv of KC8 in the presence of one equiv of cAAC resulted in the stable dimethylsiliconchloride monoradical (cAAC)Me2SiCl (2). [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Sinhababu, Soumen and Kundu, Subrata and Siddiqui, Mujahuddin M. and Paesch, Alexander N. and Herbst-Irmer, Regine and Schwederski, Brigitte and Saha, Pinaki and Zhao, Lili and Frenking, Gernot and Kaim, Wolfgang and Stalke, Dietmar and Roesky, Herbert W.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/25bcf725af942fcb73c57dc589b080f83/huebleriac}, doi = {10.1039/c9cc01448a}, interhash = {c8ae395be3eef839864b3934f0bc15a2}, intrahash = {5bcf725af942fcb73c57dc589b080f83}, issn = {1359-7345}, journal = {Chemical Communications (Cambridge, United Kingdom)}, keywords = {alkylaminocarbene biradical cAAC complex complex;EPR complex;mol complex;silylene crystal cyclic prepn radical silylene spectra stabilized structure}, number = 31, pages = {4534--4537}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Synthesis of cAAC stabilized biradical of {\textquotedbl}Me2Si{\textquotedbl} and {\textquotedbl}Me2SiCl{\textquotedbl} monoradical from Me2SiCl2 - an important feedstock material}, volume = 55, year = 2019 }