%0 Journal Article %1 Leboschka.2009b %A Leboschka, Markus %A Sieger, Monika %A Sarkar, Biprajit %A Niemeyer, Mark %A Schurr, Thilo %A Fiedler, Jan %A Zalis, Stanislav %A Kaim, Wolfgang. %D 2009 %J Zeitschrift fuer Anorganische und Allgemeine Chemie %K complex complex;cyclic complex;silver copper crystal phenylselenomethylbenzimidazole prepn silver structure voltammetry %N 6-7 %P 1001--1007 %R 10.1002/zaac.200900098 %T Silver(I), copper(I) and copper(II) complex of the new N,Se-chelate ligand 2-phenylselenomethyl-1H-benzimidazole: Electrochemistry and structure %V 635 %X 2-Phenylselenomethyl-1H-benzimidazole (psbi) can form complexes in 2:1 ratio with coinage metal ions. Crystal structure anal. revealed a flattened metal coordination for [AgI(psbi)2](BF4) (1), approaching a distorted-planar arrangement with weak Ag-Se bonds (d \textgreater 2.9 \AA) and confirmed as energy min. by DFT calcns. The typical Jahn-Teller system [CuII(psbi)2Cl2] (2) exhibits a planar CuN2Cl2 core with weak Se···Cu···Se axial ligation [3.2944(8) \AA Cu···Se distance]. The oxygen-sensitive compd. [CuI(psbi)2](BF4) (3) exhibits electrochem. reversible oxidn. in contrast to the silver(I) analog 1. [on SciFinder(R)]

@article{Leboschka.2009b, abstract = {2-Phenylselenomethyl-1H-benzimidazole (psbi) can form complexes in 2:1 ratio with coinage metal ions. Crystal structure anal. revealed a flattened metal coordination for [AgI(psbi)2](BF4) (1), approaching a distorted-planar arrangement with weak Ag-Se bonds (d {\textgreater} 2.9 {\AA}) and confirmed as energy min. by DFT calcns. The typical Jahn-Teller system [CuII(psbi)2Cl2] (2) exhibits a planar CuN2Cl2 core with weak Se···Cu···Se axial ligation [3.2944(8) {\AA} Cu···Se distance]. The oxygen-sensitive compd. [CuI(psbi)2](BF4) (3) exhibits electrochem. reversible oxidn. in contrast to the silver(I) analog 1. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Leboschka, Markus and Sieger, Monika and Sarkar, Biprajit and Niemeyer, Mark and Schurr, Thilo and Fiedler, Jan and Zalis, Stanislav and Kaim, Wolfgang.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2359aa4a8e6a164d68c7dbb104a88bb1c/huebleriac}, doi = {10.1002/zaac.200900098}, interhash = {bc447e066613d6d6b2e402eb19f36d70}, intrahash = {359aa4a8e6a164d68c7dbb104a88bb1c}, issn = {0044-2313}, journal = {Zeitschrift fuer Anorganische und Allgemeine Chemie}, keywords = {complex complex;cyclic complex;silver copper crystal phenylselenomethylbenzimidazole prepn silver structure voltammetry}, number = {6-7}, pages = {1001--1007}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Silver(I), copper(I) and copper(II) complex of the new N,Se-chelate ligand 2-phenylselenomethyl-1H-benzimidazole: Electrochemistry and structure}, volume = 635, year = 2009 }