Ligand-mediated coupling of organometallic reaction centers
, , und .
Angewandte Chemie, International Edition in English 36 (22): 2493--2495 (1997)

In a systematic attempt to extend the coupling of electron transfer sites to the coupling of redox reaction centers through conjugated bridging ligands, (C5Me5)ClRh(m-L)RhCl(C5Me5)(PF6)2 (I) was prepd. from reaction of diiminopyrazine II or bis(pyridinyl)tetrazine III (m-L) and (C5Me5)RhCl22/AgPF6/acetone. I (as mixts. of cis and trans isomers) were studied by EPR and UV/Vis spectroscopy techniques and cyclic voltammetry to reveal extended and fully reversible electrochem.; the electrochem. potentials of I were reported. A communication between organometallic reaction sites in the dinuclear rhodium complexes bridged by ligands II and III is discussed. on SciFinder(R)
  • @b_schwederski
Diese Publikation wurde noch nicht bewertet.

Bewertungsverteilung
Durchschnittliche Benutzerbewertung0,0 von 5.0 auf Grundlage von 0 Rezensionen
    Bitte melden Sie sich an um selbst Rezensionen oder Kommentare zu erstellen.