%0 Journal Article %1 Albrecht.1999 %A Albrecht, Markus %A Hubler, Klaus %A Kaim, Wolfgang. %D 1999 %J Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences %K complex complex;gold crystal gold phosphine prepn structure thiomethylbenzimidazole %N 12 %P 1606--1608 %R 10.1515/znb-1999-1221 %T Coordination of the hetero(N,S)-bidentate ligand 1-methyl-2-(methylthiomethyl)-1H-benzimidazole to [(Ph3P)Au]+ exclusively through the imine nitrogen donor %V 54 %X 1-Methyl-2-(methylthiomethyl)-1H-benzimidazole (mmb) was reacted with Ph3PAuCl/AgPF6 in THF to yield [(Ph3P)Au(mmb)](PF6) which was crystallog. characterized. The Au+ ion is almost linearly coordinated by the triphenylphosphine P and the imine N atom of a monodentate mmb ligand. There is no gold(I)-sulfur bonding as the distance of $\sim$3.02 \AA indicates. Similarly, close intermetallic contacts between the gold centers are absent. Both effects are attributed to the pos. charge on the metal. [on SciFinder(R)]

@article{Albrecht.1999, abstract = {1-Methyl-2-(methylthiomethyl)-1H-benzimidazole (mmb) was reacted with Ph3PAuCl/AgPF6 in THF to yield [(Ph3P)Au(mmb)](PF6) which was crystallog. characterized. The Au+ ion is almost linearly coordinated by the triphenylphosphine P and the imine N atom of a monodentate mmb ligand. There is no gold(I)-sulfur bonding as the distance of $\sim$3.02 {\AA} indicates. Similarly, close intermetallic contacts between the gold centers are absent. Both effects are attributed to the pos. charge on the metal. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Albrecht, Markus and Hubler, Klaus and Kaim, Wolfgang.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/236a7b1e12a15c5b328148e4059ac4f04/huebleriac}, doi = {10.1515/znb-1999-1221}, interhash = {ae44f5a20bf1e47ac31b891979525859}, intrahash = {36a7b1e12a15c5b328148e4059ac4f04}, issn = {0932-0776}, journal = {Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences}, keywords = {complex complex;gold crystal gold phosphine prepn structure thiomethylbenzimidazole}, number = 12, pages = {1606--1608}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Coordination of the hetero(N,S)-bidentate ligand 1-methyl-2-(methylthiomethyl)-1H-benzimidazole to [(Ph3P)Au]+ exclusively through the imine nitrogen donor}, volume = 54, year = 1999 }