%0 Journal Article %1 Huebner.2012 %A Huebner, Ralph %A Sarkar, Biprajit %A Fiedler, Jan %A Zalis, Stanislav %A Kaim, Wolfgang. %D 2012 %J European Journal of Inorganic Chemistry %K calcn complex complex;DFT complex;ESR complex;mononuclear crystal cyclic mononuclear osmium prepn ruthenium spectra structure;UV thiophenylamidophenolate tridentate voltammetry %N 22 %P 3569-3576, S3569/1-S3569/5 %R 10.1002/ejic.201200225 %T Metal(IV) Complexes [M(LN,O,S)2]n (M = Ru, Os) of a Redox-Active o-Amidophenolate Ligand (LN,O,S)2- with Coordinating Thioether Appendix %V 2012 %X Complexes [M(LN,O,S)2] [M = Ru, Os; (LN,O,S)2- = 4,6-di-tert-butyl(2-methylthiophenylamido)-o-phenolate] were obtained and structurally characterized as metal(IV) complexes with mer-configured tridentate ligands. Two reversible oxidns. and one (Os) or two (Ru) reversible redns. were studied by EPR and UV/visible/NIR spectroelectrochem. The first redn. leads to EPR-silent MIII species, whereas the oxidn. produces iminosemiquinone complexes with ligand-centered spin and small-metal participation at the singly occupied MO. Absorptions in the visible and near-IR region are assigned with the help of time-dependent (TD)-DFT calcns. [on SciFinder(R)]

@article{Huebner.2012, abstract = {Complexes [M(LN,O,S)2] [M = Ru, Os; (LN,O,S)2- = 4,6-di-tert-butyl(2-methylthiophenylamido)-o-phenolate] were obtained and structurally characterized as metal(IV) complexes with mer-configured tridentate ligands. Two reversible oxidns. and one (Os) or two (Ru) reversible redns. were studied by EPR and UV/visible/NIR spectroelectrochem. The first redn. leads to EPR-silent MIII species, whereas the oxidn. produces iminosemiquinone complexes with ligand-centered spin and small-metal participation at the singly occupied MO. Absorptions in the visible and near-IR region are assigned with the help of time-dependent (TD)-DFT calcns. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Huebner, Ralph and Sarkar, Biprajit and Fiedler, Jan and Zalis, Stanislav and Kaim, Wolfgang.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/26e4cd4cfc8cd4b746b17ae4598d2c209/huebleriac}, doi = {10.1002/ejic.201200225}, interhash = {9e5e2b2f261b10914a488a74a92a0e27}, intrahash = {6e4cd4cfc8cd4b746b17ae4598d2c209}, issn = {1434-1948}, journal = {European Journal of Inorganic Chemistry}, keywords = {calcn complex complex;DFT complex;ESR complex;mononuclear crystal cyclic mononuclear osmium prepn ruthenium spectra structure;UV thiophenylamidophenolate tridentate voltammetry}, number = 22, pages = {3569-3576, S3569/1-S3569/5}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Metal(IV) Complexes [M(LN,O,S)2]n (M = Ru, Os) of a Redox-Active o-Amidophenolate Ligand (LN,O,S)2- with Coordinating Thioether Appendix}, volume = 2012, year = 2012 }