%0 Journal Article %1 Lahiri.2010 %A Lahiri, Goutam Kumar %A Kaim, Wolfgang. %D 2010 %J Dalton Transactions %K active complex electronic ligand nitrosyl redox review ruthenium structure %N 19 %P 4471--4478 %R 10.1039/c002173c %T Electronic structure alternatives in nitrosylruthenium complexes %V 39 %X A review. Coordination compds. [Ru(NO)Ln] contg. an electro-active metal and potentially noninnocent ligands NO (and L) can have ground state electronic structures formulated as RuIII(NO+) = RuNO5, RuII(NO+) = RuNO6, RuII(NO$\surd$) = RuNO7 or RuII(NO-) = RuNO8. The neighboring states of the RuNO6 systems can be accessed by spectroelectrochem. methods or through chem. reactions. The co-ligands Ln affect the electronic structures of the quite variable RuNO6 examples, in contrast to the more invariant RuNO7 species. Potential electro-active co-ligands L such as porphyrins or quinones provide addnl. alternatives for the electronic structures. [on SciFinder(R)]

@article{Lahiri.2010, abstract = {A review. Coordination compds. [Ru(NO)Ln] contg. an electro-active metal and potentially noninnocent ligands NO (and L) can have ground state electronic structures formulated as RuIII(NO+) = {RuNO}5, RuII(NO+) = {RuNO}6, RuII(NO$\surd$) = {RuNO}7 or RuII(NO-) = {RuNO}8. The neighboring states of the {RuNO}6 systems can be accessed by spectroelectrochem. methods or through chem. reactions. The co-ligands Ln affect the electronic structures of the quite variable {RuNO}6 examples, in contrast to the more invariant {RuNO}7 species. Potential electro-active co-ligands L such as porphyrins or quinones provide addnl. alternatives for the electronic structures. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Lahiri, Goutam Kumar and Kaim, Wolfgang.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2b63062a84a7ca70e98a3dc99db29fac8/huebleriac}, doi = {10.1039/c002173c}, interhash = {6fc42c1206c2f9b155f2f6ff0917b2ee}, intrahash = {b63062a84a7ca70e98a3dc99db29fac8}, issn = {1477-9226}, journal = {Dalton Transactions}, keywords = {active complex electronic ligand nitrosyl redox review ruthenium structure}, number = 19, pages = {4471--4478}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Electronic structure alternatives in nitrosylruthenium complexes}, volume = 39, year = 2010 }