Reaction of aromatic phosphoranylidene derivatives with electrons. I
W. Kaim. Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 36B (2):
150--156(1981)
Zusammenfassung
The compds. p-Me2P(X)C6H4P(X)Me2 (X = O, S, Se, NPh) undergo one-electron redn. at a mercury cathode or on reaction with solvated electrons in a K/18-crown-6/THF mixt. The radical anions formed are persistent and have been characterized by ESR. They may be described as complexes of the spin-bearing moiety p-Me2PC6H4PMe2̅.bul. with the coordinated groups X. on SciFinder(R)
%0 Journal Article
%1 Kaim.1981j
%A Kaim, Wolfgang.
%D 1981
%J Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie
%K ESR;phosphoranylidene electrochem phosphinylbenzene redn
%N 2
%P 150--156
%T Reaction of aromatic phosphoranylidene derivatives with electrons. I
%V 36B
%X The compds. p-Me2P(X)C6H4P(X)Me2 (X = O, S, Se, NPh) undergo one-electron redn. at a mercury cathode or on reaction with solvated electrons in a K/18-crown-6/THF mixt. The radical anions formed are persistent and have been characterized by ESR. They may be described as complexes of the spin-bearing moiety p-Me2PC6H4PMe2̅.bul. with the coordinated groups X. on SciFinder(R)
@article{Kaim.1981j,
abstract = {The compds. p-Me2P(X)C6H4P(X)Me2 (X = O, S, Se, NPh) undergo one-electron redn. at a mercury cathode or on reaction with solvated electrons in a K/18-crown-6/THF mixt. The radical anions formed are persistent and have been characterized by ESR. They may be described as complexes of the spin-bearing moiety p-Me2PC6H4PMe2̅.bul. with the coordinated groups X. [on SciFinder(R)]},
added-at = {2022-06-15T11:26:56.000+0200},
author = {Kaim, Wolfgang.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2d2b8da9b0a85b99367089ba3f9d1f5a2/huebleriac},
interhash = {256447d7eb1ac11f00bc84b681a9fbd4},
intrahash = {d2b8da9b0a85b99367089ba3f9d1f5a2},
issn = {0340-5087},
journal = {Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie},
keywords = {ESR;phosphoranylidene electrochem phosphinylbenzene redn},
number = 2,
pages = {150--156},
timestamp = {2022-06-15T09:26:56.000+0200},
title = {Reaction of aromatic phosphoranylidene derivatives with electrons. I},
volume = {36B},
year = 1981
}