A model is derived which enables the calculation of solid/fluid phase equilibria in multicomponent systems over the entire pressure range. The model requires only generally available caloric data of the pure solids. The non-ideality of the fluid phase is described using the SAFT equation of state. The model is verified on experimental phase equilibrium data of binary and ternary n-alkane mixtures as well as on the system naphthalene-CO2.
%0 Journal Article
%1 https://doi.org/10.1002/1521-4125(200106)24:6<607::AID-CEAT607>3.0.CO;2-T
%A Seiler, M.
%A Groß, J.
%A Bungert, B.
%A Sadowski, G.
%A Arlt, W.
%D 2001
%J Chemical Engineering & Technology
%K myown
%N 6
%P 607-612
%R https://doi.org/10.1002/1521-4125(200106)24:6<607::AID-CEAT607>3.0.CO;2-T
%T Modeling of Solid/Fluid Phase Equilibria in Multicomponent Systems at High Pressure
%U https://onlinelibrary.wiley.com/doi/abs/10.1002/1521-4125%28200106%2924%3A6%3C607%3A%3AAID-CEAT607%3E3.0.CO%3B2-T
%V 24
%X A model is derived which enables the calculation of solid/fluid phase equilibria in multicomponent systems over the entire pressure range. The model requires only generally available caloric data of the pure solids. The non-ideality of the fluid phase is described using the SAFT equation of state. The model is verified on experimental phase equilibrium data of binary and ternary n-alkane mixtures as well as on the system naphthalene-CO2.
@article{https://doi.org/10.1002/1521-4125(200106)24:6<607::AID-CEAT607>3.0.CO;2-T,
abstract = {A model is derived which enables the calculation of solid/fluid phase equilibria in multicomponent systems over the entire pressure range. The model requires only generally available caloric data of the pure solids. The non-ideality of the fluid phase is described using the SAFT equation of state. The model is verified on experimental phase equilibrium data of binary and ternary n-alkane mixtures as well as on the system naphthalene-CO2.},
added-at = {2024-10-28T17:35:51.000+0100},
author = {Seiler, M. and Groß, J. and Bungert, B. and Sadowski, G. and Arlt, W.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2ba5f082311977687ac14258baad7350e/jgro},
doi = {https://doi.org/10.1002/1521-4125(200106)24:6<607::AID-CEAT607>3.0.CO;2-T},
eprint = {https://onlinelibrary.wiley.com/doi/pdf/10.1002/1521-4125%28200106%2924%3A6%3C607%3A%3AAID-CEAT607%3E3.0.CO%3B2-T},
interhash = {ca7078c0532c6fc27072ae9285c46f2b},
intrahash = {ba5f082311977687ac14258baad7350e},
journal = {Chemical Engineering \& Technology},
keywords = {myown},
number = 6,
pages = {607-612},
timestamp = {2024-10-28T17:35:51.000+0100},
title = {Modeling of Solid/Fluid Phase Equilibria in Multicomponent Systems at High Pressure},
url = {https://onlinelibrary.wiley.com/doi/abs/10.1002/1521-4125%28200106%2924%3A6%3C607%3A%3AAID-CEAT607%3E3.0.CO%3B2-T},
volume = 24,
year = 2001
}
