Singly and doubly reduced forms of the four isomeric bidiazines 2,2'-bipyrazine, 3,3'-bipyridazine, 2,2'- and 4,4'-bipyrimidine have been generated in a spectroelectrochem. cell and studied by UV-visible/near-IR spectroscopy. As derivs. of 2,2'-bipyridine the compds. exhibit several groups of vibrationally structured long-wavelength bands in the paramagnetic anion radical state. The assignments and variations of transition energies depending on the diaza perturbation may be rationalized using CNDO/S CI calcns. on SciFinder(R)
%0 Journal Article
%1 Krejcik.1992
%A Krejcik, Michael
%A Zalis, Stanislav
%A Ladwig, Monika
%A Matheis, Walter
%A Kaim, Wolfgang.
%D 1992
%J Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry
%K IR IR;reduced UV bidiazine bipyrazine bipyridazine bipyrimidine isomer reduced
%N 11
%P 2007--2010
%T A study of the reduced states of four isomeric bidiazines (diaza-2,2'-bipyridines) by UV-VIS/NIR-spectroelectrochemistry
%X Singly and doubly reduced forms of the four isomeric bidiazines 2,2'-bipyrazine, 3,3'-bipyridazine, 2,2'- and 4,4'-bipyrimidine have been generated in a spectroelectrochem. cell and studied by UV-visible/near-IR spectroscopy. As derivs. of 2,2'-bipyridine the compds. exhibit several groups of vibrationally structured long-wavelength bands in the paramagnetic anion radical state. The assignments and variations of transition energies depending on the diaza perturbation may be rationalized using CNDO/S CI calcns. on SciFinder(R)
@article{Krejcik.1992,
abstract = {Singly and doubly reduced forms of the four isomeric bidiazines 2,2'-bipyrazine, 3,3'-bipyridazine, 2,2'- and 4,4'-bipyrimidine have been generated in a spectroelectrochem. cell and studied by UV-visible/near-IR spectroscopy. As derivs. of 2,2'-bipyridine the compds. exhibit several groups of vibrationally structured long-wavelength bands in the paramagnetic anion radical state. The assignments and variations of transition energies depending on the diaza perturbation may be rationalized using CNDO/S CI calcns. [on SciFinder(R)]},
added-at = {2019-07-15T13:41:23.000+0000},
author = {Krejcik, Michael and Zalis, Stanislav and Ladwig, Monika and Matheis, Walter and Kaim, Wolfgang.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/29b4fd11b0ed6cea75e9fce6ff49c1d3e/b_schwederski},
interhash = {809254d9aa5ddb13f9c21edfb5048cbc},
intrahash = {9b4fd11b0ed6cea75e9fce6ff49c1d3e},
issn = {0300-9580},
journal = {Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry},
keywords = {IR IR;reduced UV bidiazine bipyrazine bipyridazine bipyrimidine isomer reduced},
number = 11,
pages = {2007--2010},
timestamp = {2019-07-15T11:42:10.000+0000},
title = {A study of the reduced states of four isomeric bidiazines (diaza-2,2'-bipyridines) by UV-VIS/NIR-spectroelectrochemistry},
year = 1992
}
