Over the past 15 years, ring-opening metathesis polymerization (ROMP) and related techniques, such as the metathesis-based 1-alkyne polymerization and cyclopolymerization, have established themselves as highly valuable and potent tools for the synthesis of functional supports and surfaces. In this chapter, the polymerization from and to surfaces using either ROMP or 1-alkyne polymerization, as well as the synthesis of functional supports, whether inorganic or organic, is summarized. In this context, both ‘grafting-from’ and ‘grafting-to’ techniques in combination with well-defined catalytic systems suitable for these purposes will be discussed. Special consideration will be given to the specific properties of the different supports used and created, that is, silica, silicon, and organic supports and the particular requirements for the polymerization catalysts used. The obtained surface-modified materials will be discussed in view of their applications, which are so far mainly located in the areas of separation science, catalysis, and molecular electronics.
%0 Book Section
%1 BUCHMEISER2012597
%A Buchmeiser, M.R.
%B Polymer Science: A Comprehensive Reference
%C Amsterdam
%D 2012
%E Matyjaszewski, Krzysztof
%E Möller, Martin
%I Elsevier
%K
%P 597-632
%R https://doi.org/10.1016/B978-0-444-53349-4.00098-4
%T 4.23 - Current and Forthcoming Applications of ROMP-Derived Polymers: Functional Surfaces and Supports
%U https://www.sciencedirect.com/science/article/pii/B9780444533494000984
%X Over the past 15 years, ring-opening metathesis polymerization (ROMP) and related techniques, such as the metathesis-based 1-alkyne polymerization and cyclopolymerization, have established themselves as highly valuable and potent tools for the synthesis of functional supports and surfaces. In this chapter, the polymerization from and to surfaces using either ROMP or 1-alkyne polymerization, as well as the synthesis of functional supports, whether inorganic or organic, is summarized. In this context, both ‘grafting-from’ and ‘grafting-to’ techniques in combination with well-defined catalytic systems suitable for these purposes will be discussed. Special consideration will be given to the specific properties of the different supports used and created, that is, silica, silicon, and organic supports and the particular requirements for the polymerization catalysts used. The obtained surface-modified materials will be discussed in view of their applications, which are so far mainly located in the areas of separation science, catalysis, and molecular electronics.
%@ 978-0-08-087862-1
@incollection{BUCHMEISER2012597,
abstract = {Over the past 15 years, ring-opening metathesis polymerization (ROMP) and related techniques, such as the metathesis-based 1-alkyne polymerization and cyclopolymerization, have established themselves as highly valuable and potent tools for the synthesis of functional supports and surfaces. In this chapter, the polymerization from and to surfaces using either ROMP or 1-alkyne polymerization, as well as the synthesis of functional supports, whether inorganic or organic, is summarized. In this context, both ‘grafting-from’ and ‘grafting-to’ techniques in combination with well-defined catalytic systems suitable for these purposes will be discussed. Special consideration will be given to the specific properties of the different supports used and created, that is, silica, silicon, and organic supports and the particular requirements for the polymerization catalysts used. The obtained surface-modified materials will be discussed in view of their applications, which are so far mainly located in the areas of separation science, catalysis, and molecular electronics.},
added-at = {2025-01-22T12:51:45.000+0100},
address = {Amsterdam},
author = {Buchmeiser, M.R.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/28ad0fdb49e5be9b912fb80212adccb18/dwang},
booktitle = {Polymer Science: A Comprehensive Reference},
doi = {https://doi.org/10.1016/B978-0-444-53349-4.00098-4},
editor = {Matyjaszewski, Krzysztof and Möller, Martin},
interhash = {f44d56a3499dac3c901ae399dda0ef41},
intrahash = {8ad0fdb49e5be9b912fb80212adccb18},
isbn = {978-0-08-087862-1},
keywords = {},
pages = {597-632},
publisher = {Elsevier},
timestamp = {2025-01-22T12:51:45.000+0100},
title = {4.23 - Current and Forthcoming Applications of ROMP-Derived Polymers: Functional Surfaces and Supports},
url = {https://www.sciencedirect.com/science/article/pii/B9780444533494000984},
year = 2012
}
