%0 Journal Article %1 Bino.1979 %A Bino, Avi %A Cotton, F. Albert %A Kaim, Wolfgang. %D 1979 %J Journal of the American Chemical Society %K acetamidatochromium bond carboxamidato chromium complex;chromium complex;substituent crystal distance effect prepn quadruple structure;bond %N 9 %P 2506--2507 %R 10.1021/ja00503a056 %T The \dqsupershort\dq chromium-to-chromium quadruple bond: Its occurrence in a tetracarboxamidatodichromium(II) compound %V 101 %X Cr2(PhNAc)4, the 1st compd. contg. a M-M quadruple bond bridged by amino groups, was prepd. and its structure detd. by x-ray crystallog. The Cr-Cr distance is 1.873(4) \AA. The much longer Cr-Cr bonds in Cr2(O2CR)4 compds. may be due solely to the presence of axial bonds to the Cr atoms; such bonds are prevented here by the bulky Ph groups. [on SciFinder(R)]

@article{Bino.1979, abstract = {Cr2(PhNAc)4, the 1st compd. contg. a M-M quadruple bond bridged by amino groups, was prepd. and its structure detd. by x-ray crystallog. The Cr-Cr distance is 1.873(4) {\AA}. The much longer Cr-Cr bonds in Cr2(O2CR)4 compds. may be due solely to the presence of axial bonds to the Cr atoms; such bonds are prevented here by the bulky Ph groups. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Bino, Avi and Cotton, F. Albert and Kaim, Wolfgang.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/289def98730a7a2d0905295a0b63688b5/huebleriac}, doi = {10.1021/ja00503a056}, interhash = {109fb10165266d06a7ed03660e296e0e}, intrahash = {89def98730a7a2d0905295a0b63688b5}, issn = {0002-7863}, journal = {Journal of the American Chemical Society}, keywords = {acetamidatochromium bond carboxamidato chromium complex;chromium complex;substituent crystal distance effect prepn quadruple structure;bond}, number = 9, pages = {2506--2507}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {The {\dq}supershort{\dq} chromium-to-chromium quadruple bond: Its occurrence in a tetracarboxamidatodichromium(II) compound}, volume = 101, year = 1979 }