Radical ions, XXI. ESR investigation of trimethylsilylmethyl or trimethylsilyl substituted radical cations of anthracene, biphenyl, and 9,10-dihydroanthracene
W. Kaim, und H. Bock. Chemische Berichte, 111 (11):
3585--3595(1978)
Zusammenfassung
The radical cations of I, II and cis- and trans-III were generated via 1-electron oxidn. using AlCl3 in CH2Cl2. ESR spectra can be assigned via HMO models and confirm extensive spin delocalization as well as restricted conformational flexibility. A dihedral angle of $\sim$125° is estd. for I radical cation. [on SciFinder(R)]
%0 Journal Article
%1 Kaim.1978d
%A Kaim, Wolfgang
%A Bock, Hans.
%D 1978
%J Chemische Berichte
%K ESR arom cation radical trimethylsilyl
%N 11
%P 3585--3595
%T Radical ions, XXI. ESR investigation of trimethylsilylmethyl or trimethylsilyl substituted radical cations of anthracene, biphenyl, and 9,10-dihydroanthracene
%V 111
%X The radical cations of I, II and cis- and trans-III were generated via 1-electron oxidn. using AlCl3 in CH2Cl2. ESR spectra can be assigned via HMO models and confirm extensive spin delocalization as well as restricted conformational flexibility. A dihedral angle of $\sim$125° is estd. for I radical cation. [on SciFinder(R)]
@article{Kaim.1978d,
abstract = {The radical cations of I, II and cis- and trans-III were generated via 1-electron oxidn. using AlCl3 in CH2Cl2. ESR spectra can be assigned via HMO models and confirm extensive spin delocalization as well as restricted conformational flexibility. A dihedral angle of $\sim$125° is estd. for I radical cation. [on SciFinder(R)]},
added-at = {2022-06-15T11:26:56.000+0200},
author = {Kaim, Wolfgang and Bock, Hans.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/282bd33009085c81308639f88683f3269/huebleriac},
interhash = {85505f8ac4090041f681eba7f56c9a8e},
intrahash = {82bd33009085c81308639f88683f3269},
issn = {0009-2940},
journal = {Chemische Berichte},
keywords = {ESR arom cation radical trimethylsilyl},
number = 11,
pages = {3585--3595},
timestamp = {2022-06-15T09:26:56.000+0200},
title = {Radical ions, XXI. ESR investigation of trimethylsilylmethyl or trimethylsilyl substituted radical cations of anthracene, biphenyl, and 9,10-dihydroanthracene},
volume = 111,
year = 1978
}