%0 Journal Article %1 Kaim.2013 %A Kaim, Wolfgang %A Sarkar, Biprajit. %D 2013 %J Coordination Chemistry Reviews %K element mixed osmium review valency %N 9-10 %P 1650--1659 %R 10.1016/j.ccr.2012.08.026 %T Mixed valency of a 5d element: The osmium example %V 257 %X A review. Pronounced spin-orbit coupling effects and the stabilization of higher oxidn. states for the osmium analogs of mixed-valent ruthenium compds. result in more complex electronic spectra, frequent EPR silence, and valence transfer-dependent comproportionation consts. for the intermediates. [on SciFinder(R)]

@article{Kaim.2013, abstract = {A review. Pronounced spin-orbit coupling effects and the stabilization of higher oxidn. states for the osmium analogs of mixed-valent ruthenium compds. result in more complex electronic spectra, frequent EPR silence, and valence transfer-dependent comproportionation consts. for the intermediates. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Kaim, Wolfgang and Sarkar, Biprajit.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2800efb668607f352b0e11ca78aff955d/huebleriac}, doi = {10.1016/j.ccr.2012.08.026}, interhash = {3f3390806b9fc54ef77ab26e4655c4ea}, intrahash = {800efb668607f352b0e11ca78aff955d}, issn = {0010-8545}, journal = {Coordination Chemistry Reviews}, keywords = {element mixed osmium review valency}, number = {9-10}, pages = {1650--1659}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Mixed valency of a 5d element: The osmium example}, volume = 257, year = 2013 }