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First observation of resolved ESR hyperfine structure for a reduced ruthenium(II) polyazine complex

, , , und . Chemical Physics Letters, 118 (4): 431--434 (1985)
DOI: 10.1016/0009-2614(85)85405-1

Zusammenfassung

A resolved ESR spectrum of a Ru(II) polyazine radical complex was obsd. in the binuclear species ([(bpy)4Ru2(dptz)]3+ (dptz: 3,6-di-2-pyridyl-1,2,4,5-tetrazine). ESR in conjunction with HMO McLachlan calcns. reveal the localization of the unpaired electron in the tetrazine p system and a strongly polarizing effect of the [Ru(bpy)2]2+ fragment. [on SciFinder(R)]

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